Application

PRODUCT NAME	:	NITROPROPANE (2-)
CAS number	:	79-46-9
UN number	:	2608
Formula	:	CH3CHNO2CH3
Odour	:
Solubility in water	:	SLIGHTLY
Density	:	0.992 at 20 ^oC
Boiling point	:	120 ^oC
Melting point	:	-93 ^oC
Viscosity	:
Flashpoint	:	24 ^oC
Explosive limits	:	2.5 – 9 Vol%
Vapour pressure	:	17 mbar at 20 ^oC
Skin absorption/irritation	:	YES
TLV Country NL Year 1995	:	1 ppm 3.6 mg/m3
Pollution category 1994	:	D

Dosage

MSDS

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Product Name	2-Nitropropane
Part Number	RXSOL-19-1396-025

Company Details:

RX MARINE INTERNATIONAL
105, A wing , BSEL , TECH PARK.
VASHI ,NEW BOMBAY 400703 INDIA

Branch : Kandla, Mumbai , Chennai, Vizag, Kolkata, UAE , OMAN , CANADA and KENYA

Phone	+91 22 20871200 - 1400
Fax	+91 22 27612100 :::AOH :0091 9821214367
Email	mail @ rxmarine.com
Website	www.rxmraine.comA

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Chemical Name	CAS	EC number	Weight	Formula
2-Nitropropane	79-46-9	201-209-1	<= 100 %	C₃H₇NO₂

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Signal Word	Danger
Hazard Statements	H226 Flammable liquid and vapor. H302 Harmful if swallowed. H331 Toxic if inhaled. H341 Suspected of causing genetic defects. H350 May cause cancer. H412 Harmful to aquatic life with long lasting effects.
Precautionary statements	P202 Do not handle until all safety precautions have been read and understood. P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P273 Avoid release to the environment. P301 + P312 IF SWALLOWED: Call a POISON CENTER/ doctor if you feel unwell. P304 + P340 + P311 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER/ doctor. P308 + P313 IF exposed or concerned: Get medical advice/ attention.
Classification of the substance or mixture	Not a hazardous substance or mixture according to Regulation (EC) No 1272/2008.
Supplemental Hazard Statements	None.
Other hazards	This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.

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General advice	First aiders need to protect themselves. Show this material safety data sheet to the doctor in attendance.
If inhaled	After inhalation: fresh air. Immediately call in physician. If breathing stops: immediately apply artificial respiration, if necessary also oxygen.
Eye Contact	After eye contact: rinse out with plenty of water. Call in ophthalmologist. Remove contact lenses.
Swallowed	After swallowing: immediately make victim drink water (two glasses at most). Consult a physician.
Skin Contact	In case of skin contact: Take off immediately all contaminated clothing. Rinse skin with water/ shower. Consult a physician.
Inhalation	Remove patient to fresh air, keep warm and at rest and get medical assistance in necessary.
Ingestion	Rinse mouth with water. Do not induce vomiting. Never give anything by mouth to an unconscious person. Call a doctor or Poison Control Center immediately.
Most important symptoms and effects, both acute and delaye	The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in section 11
Indication of any immediate medical attention and special treatment needed	No data available

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Flammability	Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
Suitable extinguishing media	Water Foam Carbon dioxide (CO2) Dry powder
Unsuitable extinguishing media	For this substance/mixture no limitations of extinguishing agents are given.
Special hazards arising from the substance or mixture	Carbon oxides Nitrogen oxides (NOx) Combustible. Vapors are heavier than air and may spread along floors. Forms explosive mixtures with air at elevated temperatures. Development of hazardous combustion gases or vapours possible in the event of fire.
Further information	Remove container from danger zone and cool with water. Suppress (knock down) gases/vapors/mists with a water spray jet. Prevent fire extinguishing water from contaminating surface water or the ground water system.
Hazardous combustion products	Fire may cause the evolution of Sulphur oxides, nitrogen oxides.
Advice for firefighters	Stay in danger area only with self-contained breathing apparatus. Prevent skin contact by keeping a safe distance or by wearing suitable protective clothing.
Protective Equipment	Use personal protective equipment.
Specific Hazards Arising from the Chemical	Oxides of phosphorus Sodium oxides Not combustible. Fire may cause evolution of: Oxides of phosphorus Ambient fire may liberate hazardous vapours.

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Personal precautions, protective equipment and emergency procedures	Advice for non-emergency personnel: Do not breathe vapors, aerosols. Avoid substance contact. Ensure adequate ventilation. Keep away from heat and sources of ignition. Evacuate the danger area, observe emergency procedures, consult an expert. For personal protection see section 8.
Spillage	Oxidizing material. Stop leak if without risk. Avoid contact with a combustible material (wood, paper, oil, clothing...). Keep substance damp using water spray. Do not touch spilled material. Prevent entry into sewers, basements or confined areas dike if needed. Eliminate all ignition sources. Call for assistance on disposal.
Enviromental Precaution	Do not let product enter drains. Risk of explosion.
Methods and materials for containment and cleaning	Cover drains. Collect, bind, and pump off spills. Observe possible material restrictions (see sections 7 and 10). Take up carefully with liquid-absorbent material (e.g. Chemizorb®). Dispose of properly. Clean up affected area.

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Advice on protection against fire and explosion	Keep away from open flames, hot surfaces and sources of ignition.Take precautionary measures against static discharge.
Incompatible materials	Keep away from alkalis, strong oxidizing agents and metals. Provide containment walls of adequate capacity to hold any accidental spills.
Hygiene measures	Immediately change contaminated clothing. Apply preventive skin protection. Wash hands and face after working with substance. For precautions see section 2.2.
Precautions for safe handling	Work under hood. Do not inhale substance/mixture. Avoid generation of vapours/aerosols.
Storage conditions	Keep container tightly closed in a dry and well-ventilated place. Keep away from heat and sources of ignition. Keep locked up or in an area accessible only to qualified or authorized persons.
Storage class	Storage class (TRGS 510): 3: Flammable liquids
Specific end use(s)	Apart from the uses mentioned in section 1.2 no other specific uses are stipulate
Advice on general occupational hygiene	Keep away from sources of ignition - No smoking.Take measures to prevent the build up of electrostatic charge.
Requirements for storage	Keep in cool and store under shade.

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Exposure controls	Appropriate engineering controls Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday.
Control parameters	Ingredients with workplace control parameters Contains no substances with occupational exposure limit values.
Engineering Control	Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday.
Eye/face protection	Face shield and safety glasses Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU).
Body Protection	Flame retardant antistatic protective clothing.
Skin protection	Required
Respiratory protection	Where risk assessment shows air-purifying respirators are appropriate use a fullface respirator with multi-purpose combination (US) or type ABEK (EN 14387) respirator cartridges as a backup to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air respirator. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU).
Other Protection Measure	Handle in accordance with good industrial hygiene and safety practice.
Control of environmental exposure	Prevent further leakage or spillage if safe to do so. Do not let product enter drains.

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Physical state	Liquid
Colour	Colorless
Odour	Mild
Odor Threshold	No data available
pH	No data available
Melting Point	93 °C - lit.
Boiling Point	120 °C - lit.
Flash Point	26 °C - closed cup
Evaporation Rate	Not Applicable
Flammability (solid, gas)	No data available
Explosive limits	No Data Available
Upper/lower flammability or explosive limits	2,6 %(V)
Autoignition temperature	389 - 399 °C at 999,0 - 1010,40 hPa
Decomposition temperature	No data available
Vapour pressure	17 hPa at 20 °C
Density	0,992 g/mL at 25 °C - lit.
Relative Density	No data available
Relative vapor density	3,08 - (Air = 1.0)
Freezing point	No data available
Viscosity dynamic	No data available
Partition coefficient	log Pow: 1,35 at 20 °C
Explosive properties	No data available
Solubility	17,4 g/l at 25 °C - soluble
Ignition temperature	No information available.
Particle characteristics	No data available

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Reactivity	Vapor/air-mixtures are explosive at intense warming.
Stability	The product is chemically stable under standard ambient conditions (room temperature) .
Possibility of hazardous reactions	No data available
Conditions to avoid	Heating.
Incompatible materials	Strong oxidizing agents, Strong bases, Copper
Hazardous decomposition products	In the event of fire: see section 5

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Acute toxicity	LD50 Oral - Rat - 565 - 885 mg/kg LC50 Inhalation - Rat - female - 4 h - 3,21 mg/l - vapor LD50 Dermal - Rabbit - male and female - > 2.000 mg/kg
Skin corrosion/irritation	Skin - Rabbit Result: No skin irritation - 24 h
Serious eye damage/eye irritation	Eyes - Rabbit Result: Mild eye irritation
Respiratory or skin sensitization	- Guinea pig Result: Does not cause skin sensitization.
Toxic Effects on Human	May cause damage to the following organs: upper respiratory tract. Other Toxic Effects on Humans: Hazardous in case of skin contact (irritant, sensitizer), of ingestion, of inhalation (lung irritant, lung sensitizer).
Carcinogenicity	This product is or contains a component that has been reported to be probably carcinogenic based on its IARC, OSHA, ACGIH, NTP, or EPA classification. Possible human carcinogen
Germ cell mutagenicity	In vitro tests showed mutagenic effects Test Type: Ames test Test system: S. typhimurium Metabolic activation: with and without metabolic activation Result: positive
Reproductive toxicity	No data available
Specific target organ toxicity - single exposure	May cause respiratory irritation.
Special Remarks on other Toxi Effects on Humans	Acute Potential Health Effects: Skin: Causes skin irritation. May cause skin sensitization, an allergic reation, which becomes evident upon re-exposure to this material. Eyes: Causes eye irritation. Ingestion: Causes gastrointestinal (digestive) tract irritation with nausea, vomiting, and diarrhea. May be harmful if swallowed. Inhalation: Causes respiratory tract irritation. May cause chemical pneumonitis and pulmonary edema, inflammation, edema of bronchi and larynx. Chronic Potential Health Effects: Repeated or prolonged skin exposure may cause allergic reactions in sensitive individuals. Repeated or prolonged exposure by inhalation may affect respiration and metabolism.
Endocrine disrupting properties	The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher. RTECS: TZ5250000 Liver injury may occur., Cough, Shortness of breath, Headache, Nausea, Vomiting, To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

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Bioaccumulative potential	Bioaccumulation Lepomis macrochirus - 14 d at 16 °C - 0,957 mg/l(1,2-Dichloroethane) Bioconcentration factor (BCF): 2
Persistence and degradability	Biodegradability aerobic - Exposure time 28 d Result: 18 % - Not readily biodegradable. (OECD Test Guideline 301F)
Toxicity to fish	Flow-through test LC50 - Oncorhynchus mykiss (rainbow trout) - 227 mg/l - 96 h (OECD Test Guideline 203)
Toxicity to daphnia and other aquatic invertebrates	Static test EC50 - Daphnia magna (Water flea) - 380 mg/l - 48 h (OECD Test Guideline 202)
Toxicity to algae	Static test EC50 - Pseudokirchneriella subcapitata - 345 mg/l - 96 h
Toxicity to bacteria	Respiration inhibition EC50 - Sludge Treatment - 310 mg/l - 30 h (OECD Test Guideline 209)
Mobility in soil	No Information available
Results of PBT and vPvB assessment	This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.
Endocrine disrupting properties	The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher.
Other adverse effects	No data available

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Disposal methods	The material can be disposed of by removal to a licensed chemical destruction plant or by controlled incineration with flue gas scrubbing. Do not contaminate water, foodstuffs, feed or seed by storage or disposal. Do not discharge to sewer systems.
Contaminated packaging	Dispose of as unused product.
Waste treatment Method	Burn in a chemical incinerator equipped with an afterburner and scrubber but exert extra care in igniting as this material is highly flammable. Offer surplus and non-recyclable solutions to a licensed disposal company.

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UN number	ADR/RID:2608 IMDG:2608 IATA:2608
UN proper shipping name	ADR/RID:Nitropropanes IMDG:Nitropropanes IATA:Nitropropanes
Transport hazard class(es)	ADR/RID: 3 IMDG: 3 IATA: 3
Packaging group	ADR/RID: III IMDG: III IATA: III
Environmental hazards	ADR/RID: NO IMDG: NO IATA: NO
Further information	No data available

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Inventory status	Components are on the following inventories: Polymaleic acid: - US TSCA, Canadian DSL, EU EINECS, Australian AICS, Korean, Philippine PICCS and Chinese Xi irritant R 36/38 Irritant to eyes & skin R 41 Risk of serious damage to eyes S24/25 Avoid contact with skin and eyes S26/28 In case of contact eyes & skin, rinse with plenty water and seek medical advice Section 312/313: Not listed. Not listed under California proposition 65.
Safety, health and environmental regulations/legislation specific for the substance or mixture	This material safety data sheet complies with the requirements of Regulation (EC) No. 1907/2006.
National legislation	Seveso III: Directive 2012/18/EU of the European Parliament and of the Council on the control of major-accident hazards involving dangerous substances. : ACUTE TOXIC : FLAMMABLE LIQUIDS
Other regulations	Observe work restrictions regarding maternity protection in accordance to Dir 92/85/EEC or stricter national regulations where applicable. Take note of Dir 94/33/EC on the protection of young people at work.
Chemical Safety Assessment	For this product a chemical safety assessment was not carried out.

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Other Information

The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and weassume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Rx Marine International has been advised of the possibility of such damages.

DISCLAIMER OF LIABILITY :The information in this SDS was obtained from sources which we believe are reliable. However, the information is provided without any warranty, express or implied, regarding its correctness. The conditions or methods of handling, storage, use or disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way connected with the handling, storage, use or disposal of the product. This MSDS was prepared and is to be used only for this product. If the product is used as a component in another product, this MSDS information may not be applicable.