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Corroision Inhibitor for Closed/Chilled Systems with Nitrite & Indicator

RXSOL new formulation  for removal of copper stains has been developed, Copper reacts with oxygen from air of presence of moisture to form copper oxide which is greenish in color. Never USE common acidic materials to clean Copper, As after cleaning of STAIN from Acid it will turn into BLACK.

Cooling Water Chemical-43

Corroision Inhibitor for Closed/Chilled Systems with Nitrite & Indicator

Part No: RXSOL-40-4020-025

Never USE common acidic materials to clean Copper, As after cleaning of STAIN from Acid it will turn into BLACK

RXSOL new formulation  for removal of copper stains has been developed, Copper reacts with oxygen from air of presence of moisture to form copper oxide which is greenish in color. Never USE common acidic materials to clean Copper, As after cleaning of STAIN from Acid it will turn into BLACK.

Dosage

The chemical cleaning of copper stained by a new developed product of RXSOL is Easy and Safe.

MSDS

Heading1 - Varanasi Chemical

Porduct Name               Copper Stain Remover
Part Number   RXSOL-41-8967-025

Company Details:

RX MARINE INTERNATIONAL
105, A wing , BSEL , TECH PARK.
VASHI ,NEW BOMBAY 400703 INDIA

Branch : Kandla, Mumbai , Chennai, Vizag, Kolkata, Fujairah, Muscat

Phone +91 22 20871200 - 1400
Fax +91 22 27612100 :::AOH :0091 9821214367
Email mail @ rxmarine.com
Website www.rxmraine.com

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Chemical Name                 Cas No                        Weight Percentage                      
Ammonium Nitrate 6484-52-2 10-20
Monoethanolamine 141-43-5 5-10
EthyleneDiAmine 107-15-3 5-10
Ammonium hydroxide solution 1336-21-6 5-10
Proprietory Blend --- 30-45

Ethylenediamine forms a chelate bis-complex with copper II

Heading3 - Varanasi Chemical
Signal Word  Danger
Hazard Statements H314 Causes severe skin burns and eye damage H318 Causes serious eye damage
Precautionary statements   P260 Do not breathe dust/fume/gas/mist/vapours/spray P264 Wash hands thoroughly after handling P280 Wear protective gloves/protective clothing/eye protection/face protection P310 Immediately call a POISON CENTER or doctor/physician P321 Specific treatment (see Section 4 on this label) P363 Wash contaminated clothing before reuse P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing  P305+P351+P338 IF IN EYES: Rinse continuously with water for several minutes. Remove contact lenses if present and easy to do – continue rinsing P405 Store locked up P501 Dispose of contents/container in accordance with local/ regional/ national/, regulations
Classification of  the substance or  mixture No data available
Supplemental Hazard    Statements No data available
Other hazards  This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher  

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General advice Show this material safety data sheet to the doctor in attendance. 
If inhaled No data available
Eye Contact  In case of eye contact, flush the eyes with water for fifteen (15) minutes. If contact lenses are worn, quickly remove them, then flush the eyes with water. Have a physician examine the eyes
Swallowed No data available
Skin Contact   Immediately remove any clothing soiled by the product. Immediately wash with water and soap and rinse thoroughly. Rinse until skin no longer feels slippery. If skin irritation continues, consult a doctor.
Inhalation Take affected persons out into the fresh air. Supply fresh air; consult doctor in case of complaints. Provide oxygen treatment if affected person has difficulty breathing. In case of irregular breathing or respiratory arrest provide artificial respiration. In case of unconsciousness place patient stably in side position for transportation. 
Ingestion If material is ingested, rinse out mouth with water and seek immediate medical attention. Do not induce vomiting but if vomiting occurs spontaneously, keep the head below the hips to prevent aspiration of liquid into the lungs. If victim is conscious drink large quantities of water to dilute stomach contents. Notes to Physician:If swallowed, gastric irrigation with added, activated carbon. If swallowed or in case of vomiting, danger of entering the lungs. If necessary oxygen respiration treatm
Most important symptoms and effects, both acute and delaye No data available
Indication of any immediate medical attention and special treatment needed  No data available

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Flammability                         No data available
Suitable extinguishing  media  This product is not inherently flammable. Use media appropriate for surrounding fire.
Unsuitable extinguishing  media For this substance/mixture no limitations of extinguishing agents are given
Unusual Fire or explosion hazard Product contains a strong oxidizer. If heated enough to evaporate the water, and explosive mixture could remain. Keep containers cool with water. Vapors are heavier than air and may travel a great distance to a source of ignition and flashback.
Further information No data available
Hazardous combustion
products
See section 10 for a list of hazardous decomposition products for this mixture. 
Advice for firefighters If evacuation of personnel is necessary, evacuate to an upwind area. Decontaminate personnel and equipment with a water wash-down after fire and smoke exposure. 
Protective Equipment Firemen and emergency responders wear full turnout gear or Level A equipment, including positive-pressure, self-contained breathing apparatus (SCBA). 
Specific Hazards Arising from the Chemical No data available

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Personal precautions,    protective equipment and    emergency procedures No data available
Spillage Spill supervisor Ensure cleanup personnel wear all appropriate Personal Protective Equipment (PPE), including respiratory protection. Keep nonessential personnel away from the contaminated area. Spilled product may be very slippery! 
Small spills Ventilate the contaminated area. Mix the appropriate sorbent into the spilled material. Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust). Collect the saturated sorbent and transfer it into a covered container. Steel containers are acceptable for all wastes except wastes which contain acid. Use suitable plastic containers for acid-bearing wastes. Dispose of the waste in compliance with all Federal, state, regional, and local regulations.
Large spills Prevent this material from entering sewers and watercourses by diking or impounding the spilled material. Advise authorities if the product has entered or may enter, sewers, watercourses, or extensive land areas. Ventilate the contaminated area. Mix the appropriate sorbent into the spilled material. Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust). Collect the saturated sorbent and transfer it into a covered container. Steel containers are acceptable for all wastes except wastes which contain acid. Use suitable plastic containers for acid-bearing wastes. Label the waste container. Dispose of the waste in compliance with all Federal, state, regional, and local regulations. 
Methods and materials for
containment and cleaning
No data available
Reference to other  sections    No data available

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Advice on protection against    fire and explosion No data available
Incompatible materials  No data available
Hygiene measures Immediately change contaminated clothing. Apply preventive skin protection. Wash hands and face after working with substance. For precautions see section 2.2.
Safe handling Wear all appropriate Personal Protective Equipment (PPE). Wear respiratory protection or ensure adequate ventilation at all times as vapors can accumulate in confined or poorly ventilated areas. Avoid aerosolizing product. Use the product in a manner which minimizes splashes and/or the creation of dust. Keep containers closed when not in use. Store at room temperatures, i.e., 40 to 95 F (4 to 35 C). Do not allow product to come in contact with aluminum
Conditions for safe storage,      including any incompatibilities 

No data available

Storage conditions Store in a cool location. Provide ventilation for receptacles.Store away from foodstuffs. Do not store together with acids.Store in cool, dry conditions in well sealed receptacles. Keep container tightly sealed.
Storage class No data available
Specific end use(s) Apart from the uses mentioned in section 1.2 no other specific uses are stipulated
Advice on general occupational    hygiene No data available

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Exposure controls  Use only with adequate ventilation, i.e., ventilation in compliance with occupational exposure limits. Use mechanical ventilation to reduce buildup of vapors in enclosed areas.
Eye/face protection No data available
Body Protection No data available
Protective equipment Wear splash goggles. If extra protection is required, wear a face shield over the splash goggles. Face shields are effective only if worn in addition to splash goggles. Wear a chemical-resistant, butyl-rubber apron and other protective clothing, as deemed appropriate, to avoid skin contact with material. Wear chemical-resistant gloves (butyl rubber or neoprene). Protective gloves should be inspected frequently and discarded when they exhibit cuts, tears, pinholes, or signs of excessive wear. Respiratory protection may still be needed even if the local exhaust is sufficient to maintain levels of hazardous ingredients below occupational exposure limits. If needed, use a NIOSH/MSHA approved respirator equipped with a full facepiece, organic vapor cartridges (ammonia, ethanolamine), and high-efficiency, particulate air (HEPA) filters. Do not use respirators beyond their capabilities. FOR EMERGENCIES AND UNKNOWN CONCENTRATIONS, use supplied-air respiratory protection or a positive-pressure, self-contained breathing apparatus (SCBA)
Contaminated equipment
Dispose of the waste in compliance with all Federal, state, regional, and local regulations.
Other Protection  Measure No data available

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Physical state Liquid
Colour Colorless
Odour Strong ammonia
Odor Threshold No data available
pH Alkaline
Melting Point No data available
Boiling Point 38°C
Flash Point 95C
Evaporation Rate No data available
Flammability (solid, gas) No data available
Explosive limits 3% - 27%
Upper/lower flammability or explosive limits No data available
Autoignition temperature No data available
Decomposition temperature  No data available
Vapour pressure 25.3 mmHg                                       
Viscosity No data available 
Density No data available
Relative Density No data available  
Specific Gravity 1.06
Partition coefficient No data available
Explosive properties No data available 
Solubility No data available
Ignition temperature No data available 
Particle characteristics No data available 

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Reactivity                        No data available
Chemical stability Hazardous polymerization will not occur. STABLE
Possibilityof hazardous reactions No data available
Conditions to avoid Warming.                                                                           
Incompatible materials
Acids and soft metals like aluminum. . 
Hazardous product dicomposition                                                         Oxides of carbon and nitrogen

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Acute toxicity  Oral Toxicity LD50: 2,864mg/kg Inhalation Toxicity LC50: 274mg/LMonoethanolamine Oral LD50: 1,515 mg/kg (Rat, male & female) Dermal LD50: 1,025 mg/kg (Rabbit) Inhalation LC
Skin corrosion/irritation No data available
Serious eye      damage/irritation No data available
Respiratory or skin    sensitization  No data available
Carcinogenicity The following chemicals comprise 0.1% or more of this mixture and are listed and/or classified as carcinogens or potential carcinogens by NTP, IARC, OSHA (mandatory listing), or ACGIH (optional listing). CAS Number Description % Weight Carcinogen Rating
Germ  cell            mutagenicity  No data available
Reproductive toxicity  No data available
Specific target organ toxicity-single      exposure
No data available
Additional Information The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher

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Persistence and degradability No data available
Toxicity to fish  LC50 (Carp (Cyprinus carpio carpio)): 349 mg/l, Exposure time: 96 h, Test Type: semi-static test, GLP: yes
Toxicity to daphnia and other  aquatic invertebrates EC50 (Daphnia magna (Water flea)): 65 mg/l, Exposure time: 48 h, Test Type: Immobilization, Analytical monitoring: yes, Method: static, GLP: yes
Toxicity No data available
Toxicity to bacteria   No data available
Toxicity to algae EC50 (Pseudokirchneriella subcapitata): 2.8 mg/l, End point: Growth rate, Exposure time: 72 h, Test Type: static test, Analytic monitoring: yes, Method: OECD Test Guideline 201, GLP: yes 
Products Biodegradation No data available
Mobility in soil No data available
Results of PBT av PvB            assessment This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.
Endocrine disrupting      properties The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher.
Other adverse effects No data available

Heading13 - Varanasi Chemical

Disposal considerations As the US EPA, state, regional, and other regulatory agencies may have jurisdiction over the disposal of your facility's hazardous waste, it is incumbent upon you, the hazardous waste generator, to learn of and satisfy all the requirements which affect you. Dispose of the hazardous waste at a properly licensed and permitted disposal site or facility. Ensure conformity to all applicable hazardous waste disposal regulations.The US EPA Hazardous Waste Numbers which follow are applicable to this unadulterated product if the product enters the "waste stream." Refer to Title 40 of the Code of Federal Regulations, Part 261 (40 CFR 261). This part of the Code identifies solid wastes which are subject to regulation under various sections of the Code and which are subject to the notification requirements of Section 3010 of the Resource Conservation and Recovery Act (RCRA)
Waste treatment  Method No data available

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UN number ADR/RID:1760 IMDG:1760 IATA:1760
UN proper shipping name  ADR/RID:Corrosive liquids, n.o.s. (ethanolamine) IMDG:Corrosive liquids, n.o.s. (ethanolamine) IATA:Corrosive liquids, n.o.s. (ethanolamine)
Transport hazard classess     ADR/RID:8 IMDG:8 IATA: 8
Packaging group ADR/RID:lll IMDG:lll IATA:lll
Environmental hazards ADR/RID:No IMDG:No IATA:No
Special precautions for user No data available    
Further information No data available    

Heading15 - Varanasi Chemical

Safety, health and environmental regulations/legislation specific for the substance or mixture This material safety data sheet complies with the requirements of Regulation (EC) No. 1907/2006
Other regulations Take note of Dir 94/33/EC on the protection of young people at work.
Chemical Safety Assessment For this product a chemical safety assessment has been  carried out

Heading16 - Varanasi Chemical

Other Information

The information above is believed to be accurate and represents the  best information   currently    available  to us.  However,   we   make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and  weassume  no liability resulting from its use. Users should make  their  own  investigations  to determine the suitability of the information for their particular purposes. In no event shall be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if RX Marine International  has been advised of the possibility of such damages.

DISCLAIMER OF LIABILITY :The information in this SDS was obtained from sources which we believe are reliable. However, the information is provided without any warranty, express or implied, regarding its correctness. The conditions or methods of handling, storage, use or disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way connected with the handling, storage, use or disposal of the product. This MSDS was prepared and is to be used only for this product. If the product is used as a component in another product, this MSDS information may not be applicable.