Corrosion Inhibitor RX 1642 (Refinery Crude Unit Overhead)
Part No: RXSOL-81-8100-210
A colourless to pale yellow transparent liquid, available as 98% DEHA and also as 85% solution in water.
Application
Dosage
Technical Specification
MSDS

| Porduct Name | Diethyl Hydroxyl Amine N,N- DEHA |
| Part Number | RXSOL-42-5029-180 |
Company Details:
RX MARINE INTERNATIONAL
105, A wing , BSEL , TECH PARK.
VASHI ,NEW BOMBAY 400703 INDIA
Branch : Kandla, Mumbai , Chennai, Vizag, Kolkata, UAE , OMAN , CANADA and KENYA
| Phone | +91 22 20871200 - 1400 |
| Fax | +91 22 27612100 :::AOH :0091 9821214367 |
| mail @ rxmarine.com | |
| Website | www.rxmraine.com |

| Product name | Cas No | EC No | Weight | Formula |
| N,N-Diethylhydroxylamine | 3710-84-7 | 223-055-4 | 89,14 g/mol | C4H11NO |

| Signal Word | Warning |
| Hazard Statements | H226 Flammable liquid and vapor. H312 + H332 Harmful in contact with skin or if inhaled. H315 Causes skin irritation. H319 Causes serious eye irritation. |
| Precautionary statements | P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P233 Keep container tightly closed. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. P304 + P340 + P312 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER/ doctor if you feel unwell. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. |
| Classification of the substance or mixture | No data available |
| Supplemental Hazard Statements | No data available |
| Other hazards | This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher. |

| General advice | First aiders need to protect themselves. Show this material safety data sheet to the doctor in attendance |
| If inhaled | fresh air. Immediately call in physician. If breathing stops: immediately apply artificial respiration, if necessary also oxygen. |
| Eye Contact | After eye contact: rinse out with plenty of water. Remove contact lenses. |
| Swallowed | After swallowing immediately make victim drink water (two glasses at most). Consult a physician. |
| Skin Contact | In case of skin contact: Take off immediately all contaminated clothing. Rinse skin with water/ shower. |
| Inhalation | No data available |
| Ingestion | No data available |
| Most important symptoms and effects, both acute and delaye | The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in section 11 |
| Indication of any immediate medical attention and special treatment needed | No data available |

| Flammability | No data available |
| Suitable extinguishing media | Carbon dioxide (CO2) Dry powder |
| Unsuitable extinguishing media | For this substance/mixture no limitations of extinguishing agents are given |
| Special hazards arising from the substance or mixture | Carbon oxides Nitrogen oxides (NOx) Combustible. Vapors are heavier than air and may spread along floors. Forms explosive mixtures with air at elevated temperatures. Development of hazardous combustion gases or vapours possible in the event of fire. |
| Further information | Remove container from danger zone and cool with water. Prevent fire extinguishing water from contaminating surface water or the ground water system. |
|
Hazardous combustion products |
No data available |
| Advice for firefighters | Stay in danger area only with self-contained breathing apparatus. Prevent skin contact by keeping a safe distance or by wearing suitable protective clothing. |
| Protective Equipment | No data available |
| Specific Hazards Arising from the Chemical | No data available |

| Personal precautions, protective equipment and emergency procedures | Advice for non-emergency personnel: Avoid inhalation of dusts. Evacuate the danger area, observe emergency procedures, consult an expert. For personal protection see section 8. |
| Spillage | No data available |
| Personal Protection | No data available |
| Enviromental Precaution | Do not let product enter drains. Risk of explosion. |
|
Methods and materials for containment and cleaning |
Cover drains. Collect, bind, and pump off spills. Observe possible material restrictions (see sections 7 and 10). Take up dry. Dispose of properly. Clean up affected area. Avoid generation of dusts. |
| Reference to other sections | For disposal see section 13. |

| Advice on protection against fire and explosion | Keep away from open flames, hot surfaces and sources of ignition.Take precautionary measures against static discharge. |
| Incompatible materials | No data available |
| Hygiene measures | Immediately change contaminated clothing. Apply preventive skin protection. Wash hands and face after working with substance. For precautions see section 2.2. |
| Advice on safe handling | Work under hood. Do not inhale substance/mixture. Avoid generation of vapours/aerosols |
| Conditions for safe storage including any incompatibilities |
No data available |
| Storage conditions | Keep container tightly closed in a dry and well-ventilated place. Keep away from heat and sources of ignition. hygroscopic |
| Storage class | Storage class (TRGS 510) 3 Flammable liquids |
| Specific end use(s) | Apart from the uses mentioned in section 1.2 no other specific uses are stipulated |
| Advice on general occupational hygiene | No data available |

| Exposure controls | Personal protective equipment |
| Engineering Control | No data available |
| Eye/face protection | Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Safety glasses |
| Body Protection | Flame retardant antistatic protective clothing |
| Skin protection | This recommendation applies only to the product stated in the safety data sheet, supplied by us and for the designated use. When dissolving in or mixing with other substances and under conditions deviating from those stated in EN374 please contact the supplier of CE-approved gloves (e.g. KCL GmbH, D-36124 Eichenzell, Internet: www.kcl.de). Full contact Material butyl-rubber Minimum layer thickness 0,7 mm Break through time 480 min Material tested:Butoject® (KCL 898) This recommendation applies only to the product stated in the safety data sheet, supplied by us and for the designated use. When dissolving in or mixing with other substances and under conditions deviating from those stated in EN374 please contact the supplier of CE-approved gloves (e.g. KCL GmbH, D-36124 Eichenzell, Internet www.kcl.de). Splash contact Material: Viton® Minimum layer thickness 0,7 mm Break through time: 120 min Material tested Vitoject® (KCL 890 / Aldrich Z677698, Size M) |
| Respiratory protection |
Required when vapours/aerosols are generated. Our recommendations on filtering respiratory protection are based on the following standards: DIN EN 143, DIN 14387 and other accompanying standards relating to the used respiratory protection system. Recommended Filter typeFilter type AXThe entrepeneur has to ensure that maintenance, cleaning and testing of respiratory protective devices are carried out according to the instructions of the producer. These measures have to be properly documented.
|
| Other Protection Measure | No data available |

| Physical state | Liquid |
| Colour | Light yellow |
| Odour | No data available |
| Odor Threshold | No data available |
| pH | No data available |
| Melting Point | -26 - -25 °C - lit |
| Boiling Point | 125 - 130 °C - lit. |
| Flash Point | 45 °C - closed cup |
| Evaporation Rate | No data available |
| Flammability (solid, gas) | No data available |
| Explosive limits | No data Available |
| Upper/lower flammability or explosive limits | Upper explosion limit 10 %(V) Lower explosion limit1,9 %(V) |
| Autoignition temperature | No data available |
| Decomposition temperature | > 120 °C |
| Vapour pressure | 133 hPa at 81,5 °C |
| Viscosity | No data available |
| Density | 0,867 g/cm3 at 25 °C - lit. |
| Relative Density | No data available |
| Partition coefficient | Log Pow 0,43 |
| Explosive properties | No data available |
| Solubility | at 20 °C soluble |
| Ignition temperature | No data available |
| Particle characteristics | No data available |

| Reactivity | Vapors may form explosive mixture with air |
| Chemical stability | The product is chemically stable under standard ambient conditions (room temperature) |
| Possibilityof hazardous reactions | Violent reactions possible with Strong oxidizing agents |
| Conditions to avoid | Exposure to moisture may affect product quality. Heating |
| Incompatible materials |
Rubber, various plastics, silicones
|
| Hazardous decomposition products | In the event of fire: see section 5 |

| Acute toxicity | LD50 Oral - Rat - 2.190 mg/kg LC50 Inhalation - Rat - 4 h - 3140 ppm LD50 Dermal - Rabbit - 1.300 mg/kg |
| Skin corrosion/irritation | Skin - Rabbit Result Mild skin irritation Aldrich- 471593 Page 8 of 12 The life science business of Merck operates as MilliporeSigma in the US and Canada Skin - Rabbit Result: Skin irritation - 24 |
| Serious eye damage/irritation | No data available |
| Respiratory or skin sensitization | No data available |
| Carcinogenicity | No data available |
| Germ cell mutagenicity | Test Type Human Test system: leukocyte Unscheduled DNA synthesis Species: Rat Application Route Parenteral Remarks: Dominant lethal test |
| Reproductive toxicity | No data available |
| Specific target organ toxicity -single exposure |
No data available
|
| Additional Information | Assessment The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher. RTECS: NC3500000 Incoordination., Mydriasis., To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. |

| Persistence and degradability | 17 % - Not readily biodegradable. |
| Toxicity to fish | No data available |
| Toxicity to daphnia and other aquatic invertebrates | EC50 - Daphnia magna (Water flea) - 110,5 mg/l - 48 h Aldrich- 471593 Page 9 of 12 The life science business of Merck operates as MilliporeSigma in the US and Canada and other aquats |
| Toxicity | No data available |
| Toxicity to bacteria | No data available |
| Toxicity to algae | No data available |
| Products Biodegradation | No data available |
| Mobility in soil | No data available |
| Results of PBT and vPvB assessment | This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher. |
| Endocrine disrupting properties | The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher |
| Other adverse effects | No data available |

| Product | No data available |
| Contaminated packaging | No data available |
| Waste treatment Method | No data available |

| UN number |
ADR/RID:1993 IMDG:1993 IATA:1993 |
| UN proper shipping name | ADR/RID:FLAMMABLE LIQUID,N.O.S.(N,N-diethylhydroxylamine) (N,Ndiethylhydroxylamine)IMDG:FLAMMABLELIQUID,N.O.S.(N,N-diethylhydroxylamine) (N,Ndiethylhydroxylamine)IATA:FLAMMABLELIQUID,N.O.S.(N,N-diethylhydroxylamine) (N,Ndiethylhydroxylamine) |
| Transport hazard class(es) | ADR/RID:3 IMDG:3 IATA: 3 |
| Packaging group | ADR/RID:lll IMDG:lll IATA:lll |
| Environmental hazards | ADR/RID:No IMDG Marine pollutant:No IATA: No |
| Special precautions for user | Tunnel restriction code (D/E) |
| Further information | No data available |

| Safety, health and environmental regulations/legislation specific for the substance or mixture | This material safety data sheet complies with the requirements of Regulation (EC) No. 1907/2006. |
| Other regulations | Observe work restrictions regarding maternity protection in accordance to Dir 92/85/EEC or stricter national regulations where applicable. Take note of Dir 94/33/EC on the protection of young people at work. |
| Chemical Safety Assessment | A Chemical Safety Assessment was not carried out for this substance. |

| Other Information |
The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and weassume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Rx Marine International has been advised of the possibility of such damages. DISCLAIMER OF LIABILITY :The information in this SDS was obtained from sources which we believe are reliable. However, the information is provided without any warranty, express or implied, regarding its correctness. The conditions or methods of handling, storage, use or disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way connected with the handling, storage, use or disposal of the product. This MSDS was prepared and is to be used only for this product. If the product is used as a component in another product, this MSDS information may not be applicable. |