Stains Indicator Reagents-69
CRESOL RED ACS GRADE
Part No: RXSOL-69-1733-126
Methyl methacrylate (MMA) is a monomer that's also known as methacrylic acid, methyl ester. A key building block for acrylic-based polymers, MMA has applications that include safety glazing, exterior paints, vinyl impact modifiers, adhesives, illumin
Methyl methacrylate (MMA) is a monomer that's also known as methacrylic acid, methyl ester. A key building block for acrylic-based polymers, MMA has applications that include safety glazing, exterior paints, vinyl impact modifiers, adhesives, illuminated light displays, and more.
MSDS
| Product Name | Methyl Methacrylate Monomer |
| Part Number | RXSOL-19-1382-210 |
Company Details:
RX MARINE INTERNATIONAL
105, A wing , BSEL , TECH PARK.
VASHI ,NEW BOMBAY 400703 INDIA
Branch : Kandla, Mumbai , Chennai, Vizag, Kolkata, UAE , OMAN , CANADA and KENYA
| Phone | +91 22 20871200 - 1400 |
| Fax | +91 22 27612100 :::AOH :0091 9821214367 |
| mail @ rxmarine.com | |
| Website | www.rxmraine.com |
| Chemical Name | CAS | EC number | Weight | Formula |
| Methyl Methacrylate | 80-62-6 | 201-297-1 | <= 100 % | C5H8O2 |
| Signal Word | Danger |
| Hazard Statements | H225 Highly flammable liquid and vapor. H315 Causes skin irritation. H317 May cause an allergic skin reaction. H335 May cause respiratory irritation. |
| P280 Wear protective gloves.P305 + P351 + P338 | Wear eye protection/ face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. |
| Precautionary statements | P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P233 Keep container tightly closed. P240 Ground and bond container and receiving equipment. P241 Use explosion-proof electrical/ ventilating/ lighting/ equipment. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. |
| Classification of the substance or mixture | Not a hazardous substance or mixture according to Regulation (EC) No 1272/2008. |
| Supplemental Hazard Statements | None. |
| Other hazards | This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher. |
| General advice | Show this material safety data sheet to the doctor in attendance. |
| If inhaled | After inhalation: fresh air. |
| Eye Contact | After eye contact: rinse out with plenty of water. Remove contact lenses. |
| Swallowed | After swallowing: immediately make victim drink water (two glasses at most). Consult a physician. |
| Skin Contact | In case of skin contact: Take off immediately all contaminated clothing. Rinse skin with water/ shower. Consult a physician. |
| Inhalation | Remove patient to fresh air, keep warm and at rest and get medical assistance in necessary. |
| Ingestion | Rinse mouth with water. Do not induce vomiting. Never give anything by mouth to an unconscious person. Call a doctor or Poison Control Center immediately. |
| Most important symptoms and effects, both acute and delaye | The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in section 11 |
| Indication of any immediate medical attention and special treatment needed | No data available |
| Flammability | May be combustible at high temperature. |
| Suitable extinguishing media | Carbon dioxide (CO2) Foam Dry powder |
| Unsuitable extinguishing media | For this substance/mixture no limitations of extinguishing agents are given. |
| Special hazards arising from the substance or mixture | Carbon oxides Combustible. Pay attention to flashback. Vapors are heavier than air and may spread along floors. Development of hazardous combustion gases or vapours possible in the event of fire. Forms explosive mixtures with air at ambient temperatures. |
| Further information | Remove container from danger zone and cool with water. Prevent fire extinguishing water from contaminating surface water or the ground water system. |
|
Hazardous combustion products |
Fire may cause the evolution of Sulphur oxides, nitrogen oxides. |
| Advice for firefighters | Stay in danger area only with self-contained breathing apparatus. Prevent skin contact by keeping a safe distance or by wearing suitable protective clothing. |
| Protective Equipment | Use personal protective equipment. |
| Specific Hazards Arising from the Chemical |
Has a fire-promoting effect due to the release of oxygen. Ambient fire may liberate hazardous vapours. |
| Personal precautions, protective equipment and emergency procedures | Advice for non-emergency personnel: Do not breathe vapors, aerosols. Avoid substance contact. Ensure adequate ventilation. Keep away from heat and sources of ignition. Evacuate the danger area, observe emergency procedures, consult an expert. For personal protection see section 8. |
| Spillage | Oxidizing material. Stop leak if without risk. Avoid contact with a combustible material (wood, paper, oil, clothing...). Keep substance damp using water spray. Do not touch spilled material. Prevent entry into sewers, basements or confined areas dike if needed. Eliminate all ignition sources. Call for assistance on disposal. |
| Personal Protection | Advice for non-emergency personnel: Avoid inhalation of dusts. Evacuate the danger area, observe emergency procedures, consult an expert. Advice for emergency responders: Protective equipment see section 8. |
| Enviromental Precaution | Do not let product enter drains. Risk of explosion. |
|
Methods and materials for containment and cleaning |
Cover drains. Collect, bind, and pump off spills. Observe possible material restrictions (see sections 7 and 10). Take up with liquid-absorbent material (e.g. Chemizorb® ). Dispose of properly. Clean up affected area. |
| Advice on safe handling | Keep workplace dry. Do not allow product to come into contact with water. |
| Advice on protection against fire and explosion | Keep away from open flames, hot surfaces and sources of ignition.Take precautionary measures against static discharge. |
| Incompatible materials | Keep away from alkalis, strong oxidizing agents and metals. Provide containment walls of adequate capacity to hold any accidental spills. |
| Hygiene measures | Immediately change contaminated clothing. Apply preventive skin protection. Wash hands and face after working with substance. For precautions see section 2.2. |
| Precautions for safe handling | For precautions see section 2.2. |
| Conditions for safe storage, including any incompatibilities | Store the container tightly closed in a dry, cool and well-ventilated place. Store apart from foodstuff containers or incompatible materials. |
| Storage conditions | Keep container tightly closed in a dry and well-ventilated place. Keep away from heat and sources of ignition. Recommended storage temperature see product label. |
| Storage class | Storage class (TRGS 510): 3: Flammable liquids |
| Specific end use(s) | Apart from the uses mentioned in section 1.2 no other specific uses are stipulated |
| Advice on general occupational hygiene | Advice on safe handling Observe label precautions. Change contaminated clothing. Wash hands after working with substance. |
| Requirements for storage | Keep in cool and store under shade. |
Derived No Effect Level (DNEL)
| Application Area | EC number | Health effect | Value |
| Worker DNEL, longterm | inhalation | Systemic effects | 210 mg/m3 |
| Worker DNEL, longterm | dermal | Systemic effects |
Predicted No Effect Concentration (PNEC)
| Compartment | Value |
| Fresh water | < 0,94 mg/l |
| Exposure controls | No specific additional engineering controls are required. Provide good natural or artificial ventilation. |
| Engineering Control | Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below recommended exposure limits. If user operations generate dust, fume or mist, use ventilation to keep exposure to airborne contaminants below the exposure limit. |
| Eye/face protection | Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Safety glasses |
| Body Protection | Flame retardant antistatic protective clothing. |
| Skin protection | This recommendation applies only to the product stated in the safety data sheet, supplied by us and for the designated use. When dissolving in or mixing with other substances and under conditions deviating from those stated in EN374 please contact the supplier of CE-approved gloves (e.g. KCL GmbH, D-36124 Eichenzell, Internet: www.kcl.de). Splash contact Material: butyl-rubber Minimum layer thickness: 0,7 mm Break through time: 60 min Material tested:Butoject® (KCL 898) |
| Respiratory protection | Recommended Filter type: Filter A (acc. to DIN 3181) for vapours of organic compounds The entrepeneur has to ensure that maintenance, cleaning and testing of respiratory protective devices are carried out according to the instructions of the producer. These measures have to be properly documented. |
| Other Protection Measure | Handle in accordance with good industrial hygiene and safety practice. |
| Control of environmental exposure | Do not let product enter drains. Risk of explosion. |
| Physical state | Liquid |
| Colour | Colorless |
| Odour | Pungent |
| Odor Threshold | Not Applicable |
| pH | No data available |
| Melting Point | 48 °C at ca.1.013 hPa |
| Boiling Point | 100,36 °C at ca.1.013,25 hPa |
| Flash Point | 10 °C - closed cup |
| Evaporation Rate | Not Applicable |
| Flammability (solid, gas) | No data available |
| Explosive limits | No Data Available |
| Upper/lower flammability or explosive limits | 12,5 %(V) / 2,1 %(V) |
| Autoignition temperature | 435 °C at 1.013,25 hPa |
| Decomposition temperature | No data available |
| Viscosity,dynamic | 0,53 mPa.s at 20 °C |
| Vapour pressure | 37 hPa at 20 °C |
| Density | 0,94 g/cm3 at 20 °C |
| Relative Density | 0,94 at 20 °C |
| Relative Vapour Density | 3,5 at 20 °C |
| Freezing point | No data available |
| Specific Gravity | No data available |
| Partition coefficient | log Pow: 1,38 at 20 °C |
| Explosive properties | No data available |
| Solubility | 15,3 g/l at 20 °C |
| Ignition temperature | No information available. |
| Particle characteristics | No data available |
| Reactivity | Vapors may form explosive mixture with air. |
| Stability | The product is chemically stable under standard ambient conditions (room temperature) . Contains the following stabilizer(s): hydroquinone monomethyl ether (0,01 %) |
| Possibility of hazardous reactions | Risk of ignition or formation of inflammable gases or vapours with: Strong oxidizing agents Exothermic reaction with: Amines polymerisation initiators Ammonia Risk of explosion with: Aldehydes |
| Conditions to avoid | Heat, flames and sparks. Heat. Contamination Keep away from direct sunlight. Heat, flames and sparks. Extremes of temperature and direct sunlight. Warming. |
| Incompatible materials | Rubber, various plastics, Strong oxidizing agents |
| Hazardous Polymerization | In the event of fire: see section 5 |
| Acute toxicity | LD50 Oral - Rat - 7.872 mg/kg Remarks: (RTECS) LC50 Inhalation - Rat - male and female - 4 h - 29,8 mg/l - vapor Remarks: (ECHA) LC50 Inhalation - Rat - 4 h - 78.000 mg/m3 LD50 Dermal - Rabbit - male - > 5.000 mg/kg (OECD Test Guideline 402) |
| Skin corrosion/irritation | Skin - Rabbit Result: Irritating to skin. - 4 h Remarks: (ECHA) |
| Serious eye damage/eye irritation | Eyes - Rabbit Result: No eye irritation Remarks: (ECHA) |
| Respiratory or skin sensitization | Local lymph node assay (LLNA) - Mouse Result: Causes sensitization. (OECD Test Guideline 429) |
| Carcinogenicity | No data available |
| Germ cell mutagenicity | Test Type: Ames test Test system: S. typhimurium Metabolic activation: with and without metabolic activation Method: OECD Test Guideline 471 Result: negative Test Type: in vivo assay Species: Mouse Application Route: Inhalation Method: OECD Test Guideline 478 Result: negative |
| Reproductive toxicity | May damage the unborn child. Suspected of damaging fertility. |
| Specific target organ toxicity - single exposure | No data available |
| Special Remarks on other Toxi Effects on Humans | Acute Potential Health Effects: Skin: Causes skin irritation. May cause skin sensitization, an allergic reation, which becomes evident upon re-exposure to this material. Eyes: Causes eye irritation. Ingestion: Causes gastrointestinal (digestive) tract irritation with nausea, vomiting, and diarrhea. May be harmful if swallowed. Inhalation: Causes respiratory tract irritation. May cause chemical pneumonitis and pulmonary edema, inflammation, edema of bronchi and larynx. Chronic Potential Health Effects: Repeated or prolonged skin exposure may cause allergic reactions in sensitive individuals. Repeated or prolonged exposure by inhalation may affect respiration and metabolism. |
| Additional Information | The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher. Repeated dose toxicity - Rat - male - Oral - NOAEL (No observed adverse effect level) - >= 124,1 mg/kg Remarks: (ECHA) Central nervous system depression, Drowsiness, Irritability, Dizziness, Ataxia., narcosis, To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. |
| Persistence and degradability | Biodegradability aerobic - Exposure time 14 d Result: 94 % - Readily biodegradable. (OECD Test Guideline 301C) Biochemical Oxygen Demand (BOD) 140 mg/g |
| Bioaccumulative potential | No data available |
| Toxicity to fish | Flow-through test LC50 - Lepomis macrochirus (Bluegill sunfish) - 191 mg/l - 96 h Remarks: (ECHA) static test LC50 - Lepomis macrochirus (Bluegill sunfish) - 283 mg/l - 96 h Remarks: (ECHA) |
| Toxicity to daphnia and other aquatic invertebrates | Flow-through test NOEC - Daphnia magna (Water flea) - 48 mg/l - 48 h Remarks: (ECHA) flow-through test EC50 - Daphnia magna (Water flea) - 69 mg/l - 48 h Remarks: (ECHA) |
| Toxicity to algae | Static test EC50 - Pseudokirchneriella subcapitata - > 110 mg/l - 72 h (OECD Test Guideline 201) static test NOEC - Pseudokirchneriella subcapitata - > 110 mg/l - 72 h (OECD Test Guideline 201) |
| Toxicity to bacteria | Static test EC50 - activated sludge - 440 mg/l - 3 h (OECD Test Guideline 209) Remarks: The value is given in analogy to the following substances: Lithium amide |
| Mobility in soil | No Information available |
| Results of PBT and vPvB assessment | This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher. |
| Endocrine disrupting properties | The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher. |
| Other adverse effects | No data available |
| Disposal methods | The material can be disposed of by removal to a licensed chemical destruction plant or by controlled incineration with flue gas scrubbing. Do not contaminate water, foodstuffs, feed or seed by storage or disposal. Do not discharge to sewer systems. |
| Contaminated packaging | Dispose of as unused product. |
| Waste treatment Method | See www.retrologistik.com for processes regarding the return of chemicals and containers, or contact us there if you have further questions. |
| UN number | ADR/RID:1247 IMDG: 1247 IATA:1247 |
| UN proper shipping name |
ADR/RID: Methyl methacrylate monomer, stabilized IMDG:Methyl methacrylate monomer, stabilized IATA:Methyl methacrylate monomer, stabilized |
| Transport hazard class(es) | ADR/RID: 3 IMDG: 3 IATA: 3 |
| Packaging group | ADR/RID: II IMDG: II IATA: II |
| Environmental hazards | ADR/RID: No IMDG: No IATA: No |
| Special precautions for user | Tunnel restriction code : (C/E) |
| Further information | Not classified as dangerous in the meaning of transport regulations. |
| Transport in bulk according to IMOinstruments | No data available |
| Inventory status | Components are on the following inventories: Polymaleic acid: - US TSCA, Canadian DSL, EU EINECS, Australian AICS, Korean, Philippine PICCS and Chinese Xi irritant R 36/38 Irritant to eyes & skin R 41 Risk of serious damage to eyes S24/25 Avoid contact with skin and eyes S26/28 In case of contact eyes & skin, rinse with plenty water and seek medical advice Section 312/313: Not listed. Not listed under California proposition 65. |
| National legislation | Seveso III: Directive 2012/18/EU of the European Parliament and of the Council on the control of major-accident hazards involving dangerous substances. : FLAMMABLE LIQUIDS |
| Other regulations | Take note of Dir 94/33/EC on the protection of young people at work. |
| Chemical Safety Assessment | A Chemical Safety Assessment has been carried out for this substance. |
| Other Information |
The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and weassume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Rx Marine International has been advised of the possibility of such damages. DISCLAIMER OF LIABILITY :The information in this SDS was obtained from sources which we believe are reliable. However, the information is provided without any warranty, express or implied, regarding its correctness. The conditions or methods of handling, storage, use or disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way connected with the handling, storage, use or disposal of the product. This MSDS was prepared and is to be used only for this product. If the product is used as a component in another product, this MSDS information may not be applicable. |