Application

PRODUCT NAME	:	ETHYLPHENOL (P-)
CAS number	:	123-07-9
UN number	:
Formula	:	HOC6H4C2H5
Odour	:
Solubility in water	:	VERY SLIGHTLY
Density	:	at ^oC
Boiling point	:	219 ^oC
Melting point	:	46 ^oC
Viscosity	:
Flashpoint	:	104 ^oC
Explosive limits	:
Vapour pressure	:	<1 mbar at 20 ^oC
Skin absorption/irritation	:	YES
TLV Country	:
Pollution category 1994	:	(A)

Dosage

MSDS

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Product Name	ETHYL PHENOL P
Part Number	RXSOL-19-1189-025

Company Details:

RX MARINE INTERNATIONAL
105, A wing , BSEL , TECH PARK.
VASHI ,NEW BOMBAY 400703 INDIA

Branch : Kandla, Mumbai , Chennai, Vizag, Kolkata, UAE , OMAN , CANADA and KENYA

Phone	+91 22 20871200 - 1400
Fax	+91 22 27612100 :::AOH :0091 9821214367
Email	mail @ rxmarine.com
Website	www.rxmraine.com

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Chemical Name	CAS	EC number	Weight	Formula
p-Hydroxyethylbenzene	123-07-9	204-598-6	<= 100 %	C₈H₁₀O

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Signal Word	Danger
Hazard Statements	H318 Causes serious eye damage.
P280 Wear protective gloves.P305 + P351 + P338	Wear eye protection/ face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
Precautionary statements	P280 Wear eye protection/ face protection. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
Classification of the substance or mixture	Not a hazardous substance or mixture according to Regulation (EC) No 1272/2008.
Supplemental Hazard Statements	None
Other hazards	This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.

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General advice	Show this material safety data sheet to the doctor in attendance.
If inhaled	After inhalation: fresh air.
Eye Contact	After eye contact: rinse out with plenty of water. Immediately call in ophthalmologist. Remove contact lenses.
Swallowed	After swallowing: immediately make victim drink water (two glasses at most). Consult a physician.
Skin Contact	In case of skin contact: Take off immediately all contaminated clothing. Rinse skin with water/ shower.
Inhalation	Remove patient to fresh air, keep warm and at rest and get medical assistance in necessary.
Ingestion	Rinse mouth with water. Do not induce vomiting. Never give anything by mouth to an unconscious person. Call a doctor or Poison Control Center immediately.
Most important symptoms and effects, both acute and delaye	The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in section 11
Indication of any immediate medical attention and special treatment needed	No data available

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Flammability	May be combustible at high temperature.
Suitable extinguishing media	Water Foam Carbon dioxide (CO2) Dry powder
Unsuitable extinguishing media	For this substance/mixture no limitations of extinguishing agents are given.
Special hazards arising from the substance or mixture	Carbon oxides Combustible. Vapors are heavier than air and may spread along floors. Forms explosive mixtures with air on intense heating. Development of hazardous combustion gases or vapours possible in the event of fire.
Further information	Prevent fire extinguishing water from contaminating surface water or the ground water system.
Hazardous combustion products	Fire may cause the evolution of Sulphur oxides, nitrogen oxides.
Advice for firefighters	In the event of fire, wear self-contained breathing apparatus.
Protective Equipment	Use personal protective equipment.
Specific Hazards Arising from the Chemical	Has a fire-promoting effect due to the release of oxygen. Ambient fire may liberate hazardous vapours.

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Personal precautions, protective equipment and emergency procedures	Advice for non-emergency personnel: Avoid inhalation of dusts. Avoid substance contact. Ensure adequate ventilation. Evacuate the danger area, observe emergency procedures, consult an expert. For personal protection see section 8.
Spillage	Oxidizing material. Stop leak if without risk. Avoid contact with a combustible material (wood, paper, oil, clothing...). Keep substance damp using water spray. Do not touch spilled material. Prevent entry into sewers, basements or confined areas dike if needed. Eliminate all ignition sources. Call for assistance on disposal.
Personal Protection	Advice for non-emergency personnel: Avoid inhalation of dusts. Evacuate the danger area, observe emergency procedures, consult an expert. Advice for emergency responders: Protective equipment see section 8.
Enviromental Precaution	Do not let product enter drains.
Methods and materials for containment and cleaning	Cover drains. Collect, bind, and pump off spills. Observe possible material restrictions (see sections 7 and 10). Take up dry. Dispose of properly. Clean up affected area. Avoid generation of dusts.

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Advice on protection against fire and explosion	Provide appropriate exhaust ventilation at places where dust is formed.Keep away from sources of ignition - No smoking.Take measures to prevent the build up of electrostatic charge.
Incompatible materials	Keep away from alkalis, strong oxidizing agents and metals. Provide containment walls of adequate capacity to hold any accidental spills.
Hygiene measures	Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday. For precautions see section 2.2.
Precautions for safe handling	For precautions see section 2.2.
Conditions for safe storage, including any incompatibilities	Store the container tightly closed in a dry, cool and well-ventilated place. Store apart from foodstuff containers or incompatible materials.
Storage conditions	Tightly closed. Dry. Handle and store under inert gas.
Storage class	Storage class (TRGS 510): 8A: Combustible, corrosive hazardous materials.
Specific end use(s)	Apart from the uses mentioned in section 1.2 no other specific uses are stipulated.
Advice on general occupational hygiene	Advice on safe handling Observe label precautions. Change contaminated clothing. Wash hands after working with substance.
Requirements for storage	Keep in cool and store under shade.

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Exposure controls	No specific additional engineering controls are required. Provide good natural or artificial ventilation.
Engineering Control	Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below recommended exposure limits. If user operations generate dust, fume or mist, use ventilation to keep exposure to airborne contaminants below the exposure limit.
Eye/face protection	Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Tightly fitting safety goggles
Body Protection	Protective clothing
Skin protection	Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands. The selected protective gloves have to satisfy the specifications of Regulation (EU) 2016/425 and the standard EN 374 derived from it. Full contact Material: Nitrile rubber Minimum layer thickness: 0,11 mm Break through time: 480 min Material tested:Dermatril® (KCL 740 / Aldrich Z677272, Size M) Splash contact Material: Nitrile rubber Minimum layer thickness: 0,11 mm Break through time: 480 min Material tested:Dermatril® (KCL 740 / Aldrich Z677272, Size M) data source: KCL GmbH, D-36124 Eichenzell, phone +49 (0)6659 87300, e-mail sales @ kcl.de, test method: EN374 If used in solution, or mixed with other substances, and under conditions which differ from EN 374, contact the supplier of the EC approved gloves. This recommendation is advisory only and must be evaluated by an industrial hygienist and safety officer familiar with the specific situation of anticipated use by our customers. It should not be construed as offering an approval for any specific use scenario.
Respiratory protection	Required when dusts are generated. Our recommendations on filtering respiratory protection are based on the following standards: DIN EN 143, DIN 14387 and other accompanying standards relating to the used respiratory protection system. Recommended Filter type: Filter type P2 The entrepeneur has to ensure that maintenance, cleaning and testing of respiratory protective devices are carried out according to the instructions of the producer. These measures have to be properly documented.
Other Protection Measure	Handle in accordance with good industrial hygiene and safety practice.
Control of environmental exposure	Prevent further leakage or spillage if safe to do so. Do not let product enter drains.
Thermal hazards	No data available

gloves suit

Gloves Suit

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Physical state	Solidified mass or fragments
Colour	Yellowbeige
Odour	Woody, phenol-like, sweet
Odor Threshold	Not Applicable
pH	No data available
Melting Point	40 - 42 °C - lit.
Boiling Point	218 - 219 °C - lit.
Flash Point	100 °C - closed cup
Evaporation Rate	Not Applicable
Flammability (solid, gas)	No data available
Explosive limits	No Data Available
Upper/lower flammability or explosive limits	No data available
Autoignition temperature	No data available
Decomposition temperature	No data available
Viscosity, dynamic	No data available
Vapour pressure	0,17 hPa at 20 °C
Density	1,01 g/cm3 at 20 °C.
Relative density	1,06 at 20 °C -
Relative Vapour Density	4,22
Freezing point	No data available
Specific Gravity	No data available
Partition coefficient	Log Pow: 2,1 at 20 °C
Explosive properties	No data available
Solubility	7,4 g/l at 20 °C
Ignition temperature	No information available.
Particle characteristics	No data available

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Reactivity	Forms explosive mixtures with air on intense heating. A range from approx. 15 Kelvin below the flash point is to be rated as critical. The following applies in general to flammable organic substances and mixtures: in correspondingly fine distribution, when whirled up a dust explosion potential may generally be assumed.
Stability	The product is chemically stable under standard ambient conditions (room temperature) .
Possibility of hazardous reactions	No data available
Conditions to avoid	Strong heating.
Incompatible materials	Acid chlorides, Acid anhydrides, Strong oxidizing agents
Hazardous Polymerization	In the event of fire: see section 5

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Acute toxicity	LD50 Oral - Rat - male and female - > 2.000 mg/kg (OECD Test Guideline 401) Inhalation: Irritating to respiratory system. LD50 Dermal - Rabbit - > 5.000 mg/kg Remarks: (ECHA) LD50 Dermal - Rat - > 5.000 mg/kg Remarks: (HSDB)
Skin corrosion/irritation	Eyes - Rabbit Result: Risk of serious damage to eyes. Remarks: (ECHA)
Serious eye damage/eye irritation	Eyes - Rabbit Result: No eye irritation (Regulation (EC) No. 440/2008, Annex, B.5)
Respiratory or skin sensitization	Draize Test - Guinea pig Result: negative (OECD Test Guideline 406)
Carcinogenicity	No data available
Germ cell mutagenicity	Test Type: Ames test Test system: Escherichia coli/Salmonella typhimurium Metabolic activation: with and without metabolic activation Method: OECD Test Guideline 471 Result: negative Test Type: In vitro mammalian cell gene mutation test Test system: Human lymphocytes Metabolic activation: without metabolic activation Method: OECD Test Guideline 473 Result: negative Test Type: In vitro mammalian cell gene mutation test Test system: Chinese hamster lung cells Metabolic activation: with and without metabolic activation Method: OECD Test Guideline 476 Result: negative Test Type: Micronucleus test Species: Mouse Cell type: Red blood cells (erythrocytes) Application Route: Intraperitoneal Method: OECD Test Guideline 474 Result: negative
Reproductive toxicity	No data available
Specific target organ toxicity - single exposure	No data available
Special Remarks on other Toxi Effects on Humans	Acute Potential Health Effects: Skin: Causes skin irritation. May cause skin sensitization, an allergic reation, which becomes evident upon re-exposure to this material. Eyes: Causes eye irritation. Ingestion: Causes gastrointestinal (digestive) tract irritation with nausea, vomiting, and diarrhea. May be harmful if swallowed. Inhalation: Causes respiratory tract irritation. May cause chemical pneumonitis and pulmonary edema, inflammation, edema of bronchi and larynx. Chronic Potential Health Effects: Repeated or prolonged skin exposure may cause allergic reactions in sensitive individuals. Repeated or prolonged exposure by inhalation may affect respiration and metabolism.
Additional Information	The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher. RTECS: SL4040000 Depending on the intensity and duration of exposure, effects may vary from mild irritation to severe destruction of tissue., prolonged or repeated exposure can cause:, Damage to the eyes. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. Other dangerous properties can not be excluded. Handle in accordance with good industrial hygiene and safety practice.

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Persistence and degradability	Biodegradability aerobic - Exposure time 28 d Result: 87 % - Readily biodegradable. (OECD Test Guideline 310)
Toxicity to fish	Flow-through test LC50 - Pimephales promelas (fathead minnow) - 10,4 mg/l - 96 h (OECD Test Guideline 203)
Toxicity to daphnia and other aquatic invertebrates	Static test EC50 - Daphnia magna (Water flea) - 9 mg/l - 48 h (OECD Test Guideline 202)
Toxicity to algae	Static test ErC50 - Pseudokirchneriella subcapitata - > 22 mg/l - 72 h (OECD Test Guideline 201)
Products Biodegradation	The methods for determining the biological degradability are not applicable to inorganic substances.
Mobility in soil	No Information available
Results of PBT and vPvB assessment	This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.
Endocrine disrupting properties	The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher.
Other adverse effects	Discharge into the environment must be avoided.

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Disposal methods	The material can be disposed of by removal to a licensed chemical destruction plant or by controlled incineration with flue gas scrubbing. Do not contaminate water, foodstuffs, feed or seed by storage or disposal. Do not discharge to sewer systems.
Contaminated packaging	Dispose of as unused product.
Waste treatment Method	No data available

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UN number	ADR/RID: 2430 IMDG: 2430 IATA:2430
UN proper shipping name	ADR/RID:Alkylphenols, solid, n.o.s. IMDG:Alkylphenols, solid, n.o.s. IATA:Alkylphenols, solid, n.o.s.
Transport hazard class(es)	ADR/RID: 8 IMDG: 8 IATA: 8
Packaging group	ADR/RID: III IMDG: III IATA: III
Environmental hazards	ADR/RID: No IMDG: No IATA: No
Special precautions for user	Tunnel restriction code : (C/E)
Further information	Not classified as dangerous in the meaning of transport regulations.
Transport in bulk according to IMOinstruments	No data available

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Inventory status	Components are on the following inventories: Polymaleic acid: - US TSCA, Canadian DSL, EU EINECS, Australian AICS, Korean, Philippine PICCS and Chinese Xi irritant R 36/38 Irritant to eyes & skin R 41 Risk of serious damage to eyes S24/25 Avoid contact with skin and eyes S26/28 In case of contact eyes & skin, rinse with plenty water and seek medical advice Section 312/313: Not listed. Not listed under California proposition 65.
Safety, health and environmental regulations/legislation specific for the substance or mixture	This material safety data sheet complies with the requirements of Regulation (EC) No. 1907/2006.
Safety, health and environmental regulations specific for the product in question	European Inventory of Existing Commercial Chemical Substances (EINECS) -Listed.EC Inventory Listed. United States Toxic Substances Control Act (TSCA) Inventory- Listed. China Catalog of Hazardous chemicals 2015 Not- Listed. New Zealand Inventory of Chemicals (NZIoC)Listed. PICCS -Listed. Vietnam National Chemical Inventory -Listed. IECSC Listed. Korea Existing Chemicals List (KECL) -Listed.
Other regulations	Take note of Dir 94/33/EC on the protection of young people at work.
Chemical Safety Assessment	For this product a chemical safety assessment was not carried out

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Other Information

The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and weassume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Rx Marine International has been advised of the possibility of such damages.

DISCLAIMER OF LIABILITY :The information in this SDS was obtained from sources which we believe are reliable. However, the information is provided without any warranty, express or implied, regarding its correctness. The conditions or methods of handling, storage, use or disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way connected with the handling, storage, use or disposal of the product. This MSDS was prepared and is to be used only for this product. If the product is used as a component in another product, this MSDS information may not be applicable.