Application

PRODUCT NAME	:	METHYLPYRIDINE (3-)
CAS number	:	108-99-6
UN number	:	2313
Formula	:	NCHC(CH3)CHCHCH
Odour	:	UNPLEASANT
Solubility in water	:	SOLUBLE
Density	:	0.961 8C
Boiling point	:	143 ^OC
Melting point	:	-18 ^OC
Viscosity	:
Flashpoint	:	40 ^OC
Explosive limits	:
Vapour pressure	:	6 mbar at 20 ^OC
Skin absorption/irritation	:	YES
TLV Country	:
Pollution category 1994	:	C

Dosage

MSDS

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Product Name	Methyl Pyridine 3
Part Number	RXSOL-19-1377-210

Company Details:

RX MARINE INTERNATIONAL
105, A wing , BSEL , TECH PARK.
VASHI ,NEW BOMBAY 400703 INDIA

Branch : Kandla, Mumbai , Chennai, Vizag, Kolkata, UAE , OMAN , CANADA and KENYA

Phone	+91 22 20871200 - 1400
Fax	+91 22 27612100 :::AOH :0091 9821214367
Email	mail @ rxmarine.com
Website	www.rxmraine.comA

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Chemical Name	CAS	EC number	Weight	Formula
3-Methylpyridine	108-99-6	203-636-9	<= 100 %	C₆H₇N

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Signal Word	Danger
Hazard Statements	H314 Causes severe skin burns and eye damage. H311 + H331 Toxic in contact with skin or if inhaled.
Precautionary statements	P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. P304 + P340 + P310 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/ doctor. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
Classification of the substance or mixture	Not a hazardous substance or mixture according to Regulation (EC) No 1272/2008.
Supplemental Hazard Statements	None.
Other hazards	This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher

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General advice	First aiders need to protect themselves. Show this material safety data sheet to the doctor in attendance.
If inhaled	After inhalation: fresh air. Immediately call in physician. If breathing stops: immediately apply artificial respiration, if necessary also oxygen.
Eye Contact	After eye contact: rinse out with plenty of water. Immediately call in ophthalmologist. Remove contact lenses.
Swallowed	After swallowing: make victim drink water (two glasses at most), avoid vomiting (risk of perforation). Call a physician immediately. Do not attempt to neutralise.
Skin Contact	In case of skin contact: Take off immediately all contaminated clothing. Rinse skin with water/ shower. Call a physician immediately.
Inhalation	Remove patient to fresh air, keep warm and at rest and get medical assistance in necessary.
Ingestion	Rinse mouth with water. Do not induce vomiting. Never give anything by mouth to an unconscious person. Call a doctor or Poison Control Center immediately.
Most important symptoms and effects, both acute and delaye	The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in section 11
Indication of any immediate medical attention and special treatment needed	No data available

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Flammability	Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
Suitable extinguishing media	Carbon dioxide (CO2) Foam Dry powder
Unsuitable extinguishing media	For this substance/mixture no limitations of extinguishing agents are given.
Special hazards arising from the substance or mixture	Carbon oxides Nitrogen oxides (NOx) Combustible. Vapors are heavier than air and may spread along floors. Forms explosive mixtures with air at elevated temperatures. Development of hazardous combustion gases or vapours possible in the event of fire.
Further information	Remove container from danger zone and cool with water. Suppress (knock down) gases/vapors/mists with a water spray jet. Prevent fire extinguishing water from contaminating surface water or the ground water system..
Hazardous combustion products	Fire may cause the evolution of Sulphur oxides, nitrogen oxides.
Advice for firefighters	Stay in danger area only with self-contained breathing apparatus. Prevent skin contact by keeping a safe distance or by wearing suitable protective cl
Protective Equipment	Use personal protective equipment.
Specific Hazards Arising from the Chemical	Oxides of phosphorus Sodium oxides Not combustible. Fire may cause evolution of: Oxides of phosphorus Ambient fire may liberate hazardous vapours.

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Personal precautions, protective equipment and emergency procedures	Advice for non-emergency personnel: Do not breathe vapors, aerosols. Avoid substance contact. Ensure adequate ventilation. Keep away from heat and sources of ignition. Evacuate the danger area, observe emergency procedures, consult an expert. For personal protection see section 8.
Spillage	Oxidizing material. Stop leak if without risk. Avoid contact with a combustible material (wood, paper, oil, clothing...). Keep substance damp using water spray. Do not touch spilled material. Prevent entry into sewers, basements or confined areas dike if needed. Eliminate all ignition sources. Call for assistance on disposal.
Enviromental Precaution	Do not let product enter drains. Risk of explosion.
Methods and materials for containment and cleaning	Cover drains. Collect, bind, and pump off spills. Observe possible material restrictions (see sections 7 and 10). Take up carefully with liquid-absorbent material (e.g. Chemizorb®). Dispose of properly. Clean up affected area.

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Advice on protection against fire and explosion	Keep away from open flames, hot surfaces and sources of ignition.Take precautionary measures against static discharge.
Incompatible materials	Keep away from alkalis, strong oxidizing agents and metals. Provide containment walls of adequate capacity to hold any accidental spills.
Hygiene measures	Immediately change contaminated clothing. Apply preventive skin protection. Wash hands and face after working with substance. For precautions see section 2.2.
Precautions for safe handling	Work under hood. Do not inhale substance/mixture. Avoid generation of vapours/aerosols.
Storage conditions	Keep container tightly closed in a dry and well-ventilated place. Keep away from heat and sources of ignition. Keep locked up or in an area accessible only to qualified or authorized persons. hygroscopic
Storage class	Storage class (TRGS 510): 3: Flammable liquids
Specific end use(s)	Apart from the uses mentioned in section 1.2 no other specific uses are stipulated
Advice on general occupational hygiene	Advice on safe handling Observe label precautions. Change contaminated clothing. Wash hands after working with substance.
Requirements for storage	Keep in cool and store under shade.

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Exposure controls	Appropriate engineering controls Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday.
Control parameters	Ingredients with workplace control parameters Contains no substances with occupational exposure limit values.
Engineering Control	Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday.
Eye/face protection	Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Tightly fitting safety goggles
Body Protection	Flame retardant antistatic protective clothing.
Skin protection	This recommendation applies only to the product stated in the safety data sheet, supplied by us and for the designated use. When dissolving in or mixing with other substances and under conditions deviating from those stated in EN374 please contact the supplier of CE-approved gloves (e.g. KCL GmbH, D-36124 Eichenzell, Internet: www.kcl.de). Splash contact Material: butyl-rubber Minimum layer thickness: 0,7 mm Break through time: 60 min Material tested:Butoject® (KCL 898)
Respiratory protection	Recommended Filter type: Filter A (acc. to DIN 3181) for vapours of organic compounds The entrepeneur has to ensure that maintenance, cleaning and testing of respiratory protective devices are carried out according to the instructions of the producer. These measures have to be properly documented.
Other Protection Measure	Handle in accordance with good industrial hygiene and safety practice.
Control of environmental exposure	Do not let product enter drains. Risk of explosion.

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Physical state	Clear, liquid
Colour	Light yellow
Odour	Unpleasant
Odor Threshold	No data available
pH	8,5 at 100 g/l at 20 °C
Melting Point	19 °C - lit.
Boiling Point	144 °C - lit.
Flash Point	37 °C - closed cup
Evaporation Rate	Not Applicable
Flammability (solid, gas)	No data available
Explosive limits	No Data Available
Upper/lower flammability or explosive limits	No data available
Autoignition temperature	488 °C at 1.009 hPa
Decomposition temperature	No data available
Vapour pressure	5,9 hPa at 20 °C
Density	0,957 g/cm3 at 25 °C - lit.
Relative Density	No data available
Relative vapor density	3,22 - (Air = 1.0)
Freezing point	No data available
Viscosity	No data available
Partition coefficient	log Pow: 1,2 at 20 °C
Explosive properties	No data available
Solubility	20 °C soluble
Ignition temperature	No information available.
Particle characteristics	No data available

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Reactivity	Vapor/air-mixtures are explosive at intense warming.
Stability	The product is chemically stable under standard ambient conditions (room temperature) .
Possibility of hazardous reactions	A risk of explosion and/or of toxic gas formation exists with the following substances: Oxidizing agents hydrogen peroxide sulfuric acid Metals acids
Conditions to avoid	Hygroscopic Heating.
Incompatible materials	No data available
Hazardous decomposition products	In the event of fire: see section 5

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Acute toxicity	LD50 Oral - Rat - male - 630 mg/kg (OECD Test Guideline 401) LC50 Inhalation - Rat - 4 h - > 1300 - < 3300 ppm - vapor LD50 Dermal - Rabbit - > 800 - < 2.000 mg/kg (OECD Test Guideline 402)
Skin corrosion/irritation	Skin - Rabbit Result: Causes burns. Remarks: (ECHA)
Serious eye damage/eye irritation	Eyes - Rabbit Result: Risk of serious damage to eyes. Remarks: (ECHA)
Respiratory or skin sensitization	No data available
Toxic Effects on Human	May cause damage to the following organs: upper respiratory tract. Other Toxic Effects on Humans: Hazardous in case of skin contact (irritant, sensitizer), of ingestion, of inhalation (lung irritant, lung sensitizer).
Carcinogenicity	No data available
Germ cell mutagenicity	Test Type: reverse mutation assay Test system: S. typhimurium Metabolic activation: with and without metabolic activation Method: OECD Test Guideline 471 Result: negative Test Type: Micronucleus test Species: Mouse Application Route: Oral Method: OECD Test Guideline 474 Result: negative
Reproductive toxicity	No data available
Specific target organ toxicity - single exposure	Corrosive to the respiratory tract.
Special Remarks on other Toxi Effects on Humans	Acute Potential Health Effects: Skin: Causes skin irritation. May cause skin sensitization, an allergic reation, which becomes evident upon re-exposure to this material. Eyes: Causes eye irritation. Ingestion: Causes gastrointestinal (digestive) tract irritation with nausea, vomiting, and diarrhea. May be harmful if swallowed. Inhalation: Causes respiratory tract irritation. May cause chemical pneumonitis and pulmonary edema, inflammation, edema of bronchi and larynx. Chronic Potential Health Effects: Repeated or prolonged skin exposure may cause allergic reactions in sensitive individuals. Repeated or prolonged exposure by inhalation may affect respiration and metabolism.
Endocrine disrupting properties	The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher. RTECS: TJ5000000 Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin., Cough, Shortness of breath, Headache, Nausea

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Bioaccumulative potential	Bioaccumulation Cyprinus carpio (Carp) - 28 d (3-methylpyridine) Bioconcentration factor (BCF): 2,6 (OECD Test Guideline 305C)
Persistence and degradability	Biodegradability aerobic - Exposure time 28 d Result: 85 % - Readily biodegradable. (OECD Test Guideline 301B) Remarks: No data available
Toxicity to fish	Semi-static test LC50 - Brachydanio rerio (zebrafish) - 560 - 1.000 mg/l - 96 h (OECD Test Guideline 203)
Toxicity to daphnia and other aquatic invertebrates	EC50 - Daphnia magna (Water flea) - 320 mg/l - 48 h (OECD Test Guideline 202)
Toxicity to algae	Static test EC50 - Selenastrum capricornutum (green algae) - 320 mg/l - 72 h (OECD Test Guideline 201)
Toxicity to bacteria	NOEC - activated sludge - 20 mg/l - 28 d Remarks: (in analogy to similar products) The value is given in analogy to the following substances: 3- methylpyridine
Mobility in soil	No Information available
Results of PBT and vPvB assessment	This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.
Endocrine disrupting properties	The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher.
Other adverse effects	No data available

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Disposal methods	The material can be disposed of by removal to a licensed chemical destruction plant or by controlled incineration with flue gas scrubbing. Do not contaminate water, foodstuffs, feed or seed by storage or disposal. Do not discharge to sewer systems.
Contaminated packaging	Dispose of as unused product.
Waste treatment Method	See www.retrologistik.com for processes regarding the return of chemicals and containers, or contact us there if you have further questions.

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UN number	ADR/RID:2313 IMDG:2313 IATA:2313
UN proper shipping name	ADR/RID: Picolines IMDG: Picolines IATA:Picolines
Transport hazard class(es)	ADR/RID: 3 IMDG: 3 IATA: 3
Packaging group	ADR/RID: III IMDG: III IATA: III
Environmental hazards	ADR/RID: NO IMDG: NO IATA: NO
Further information	No data available

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Inventory status	Components are on the following inventories: Polymaleic acid: - US TSCA, Canadian DSL, EU EINECS, Australian AICS, Korean, Philippine PICCS and Chinese Xi irritant R 36/38 Irritant to eyes & skin R 41 Risk of serious damage to eyes S24/25 Avoid contact with skin and eyes S26/28 In case of contact eyes & skin, rinse with plenty water and seek medical advice Section 312/313: Not listed. Not listed under California proposition 65.
Safety, health and environmental regulations/legislation specific for the substance or mixture	This material safety data sheet complies with the requirements of Regulation (EC) No. 1907/2006.
National legislation	Seveso III: Directive 2012/18/EU of the European Parliament and of the Council on the control of major-accident hazards involving dangerous substances. : ACUTE TOXIC : FLAMMABLE LIQUIDS : 3-Methylpyridine
Other regulations	Observe work restrictions regarding maternity protection in accordance to Dir 92/85/EEC or stricter national regulations where applicable. Take note of Dir 94/33/EC on the protection of young people at work.
Chemical Safety Assessment	For this product a chemical safety assessment was not carried out.

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Other Information

The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and weassume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Rx Marine International has been advised of the possibility of such damages.

DISCLAIMER OF LIABILITY :The information in this SDS was obtained from sources which we believe are reliable. However, the information is provided without any warranty, express or implied, regarding its correctness. The conditions or methods of handling, storage, use or disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way connected with the handling, storage, use or disposal of the product. This MSDS was prepared and is to be used only for this product. If the product is used as a component in another product, this MSDS information may not be applicable.