Oil Spill Chem & Accessory -17
Saw Dust
Part No: RXSOL-17-1031-010
CORROSION INHIBITOR
MSDS
| Porduct Name | Cortron RN-587N |
| Part Number | RXSOL-81-3840-220 |
Company Details:....
RX MARINE INTERNATIONAL
105, A wing , BSEL , TECH PARK.
VASHI ,NEW BOMBAY 400703 INDIA
Branch : Kandla, Mumbai , Chennai, Vizag, Kolkata, UAE , OMAN , CANADA and KENYA
| Phone | +91 22 20871200 - 1400 |
| Fax | +91 22 27612100 :::AOH :0091 9821214367 |
| mail @ rxmarine.com | |
| Website | www.rxmraine.com |
| Pure substance/mixture | Mixture |
| Chemical Name | CAS-No | Concentration: (%) |
| Alkylpyridine | 68391-11-7 | 10 - 30 |
| Ethylene Glycol | 107-21-1 | 5 - 10 |
| Methanol | 67-56-1 | 5 - 10 |
| Oxydiethylenebis(Coco Alkyl-Dimethyl-Ammonium Chloride) | 68607-28-3 | 5 - 10 |
| Ethoxylated Mono-Tallow Alkyl-Amine | 61791-26-2 | 5 - 10 |
| 2-Mercaptoethanol | 60-24-2 | 5 - 10 |
| Morpholine Bottoms | 68909-77-3 | 1 - 5 |
|
Amines, polyethylenepoly-, ethoxylated, phosphonomethylated,
compds. with alkylpyridine derivs.
|
68920-95-6 | 1 - 5 |
| Isopropanol | 67-63-0 | 1 - 5 |
| Diethylammonium thioglycolate | Proprietary | 1 - 5 |
GHS Classification
| Flammable liquids | Category 3 |
| Acute toxicity (Oral) | Category 4 |
| Acute toxicity (Inhalation) | Category 4 |
| Acute toxicity (Dermal) | Category 4 |
| Skin corrosion | Category 1C |
| Serious eye damage | Category 1 |
| Skin sensitization | Category 1 |
| Carcinogenicity | Category 1B |
| Specific target organ toxicity - single exposure | Category 2 (Eyes) |
| Specific target organ toxicity - repeated exposure | Category 2 (Kidney). |
| Specific target organ toxicity - repeated exposure (Oral) | Category 2 |
GHS Label element
| Hazard Statements |
Flammable liquid and vapour. Harmful if swallowed, in contact with skin or if inhaled
Causes severe skin burns and eye damage.
May cause an allergic skin reaction.
Causes serious eye damage.
May cause cancer.
May cause damage to organs (Eyes).
May cause damage to organs through prolonged or repeated exposure if
swallowed.
May cause damage to organs (Kidney) through prolonged or repeated
exposure.
|
| Precautionary Statements |
Prevention:
Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
Ground/bond container and receiving equipment. Use explosion-proof electrical/
ventilating/ lighting/ equipment. Do not breathe
dust/fume/gas/mist/vapours/spray. Wear protective gloves/ protective clothing/
eye protection/ face protection.
Response:
IF SWALLOWED: Call a POISON CENTER or doctor/ physician if you feel
unwell. Rinse mouth. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
Immediately call a POISON CENTER or doctor/ physician. IF ON SKIN (or hair):
Take off immediately all contaminated clothing. Rinse skin with water/shower. IF
INHALED: Remove person to fresh air and keep comfortable for breathing.
Immediately call a POISON CENTER/doctor. IF IN EYES: Rinse cautiously with
water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
|
| Other hazards | None known. |
| In case of eye contact |
Rinse immediately with plenty of water, also under the eyelids, for at least 15
minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
Get medical attention immediately.
|
| In case of skin contact |
Wash off immediately with plenty of water for at least 15 minutes. Use a mild
soap if available. Wash clothing before reuse. Thoroughly clean shoes beforereuse. Get medical attention immediately.
|
| If swallowed | Rinse mouth with water. Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Get medical attention immediately. |
| If inhaled | Remove to fresh air. Treat symptomatically. Get medical attention. |
| Protection of first-aiders | In event of emergency assess the danger before taking action. Do not put yourself at risk of injury. If in doubt, contact emergency responders. Use personal protective equipment as required. |
| Notes to physician | Treat symptomatically. |
| Most important symptoms and effects, both acute and delayed | See Section 11 for more detailed information on health effects and symptoms. |
| Suitable extinguishing media | Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. |
| Unsuitable extinguishing media | None known. |
| Specific hazards during firefighting |
Highly flammable liquid and vapor. Runoff to sewer may create fire or explosion hazard.
In a fire or if heated, a pressure increase will occur and the container may burst, with the
risk of a subsequent explosion. The vapor/gas is heavier than air and will spread along
the ground. Vapors may accumulate in low or confined areas or travel a considerable
distance to a source of ignition and flash back.
Highly flammable liquid and vapor. Runoff to sewer may create fire or explosion hazard.
In a fire or if heated, a pressure increase will occur and the container may burst, with the
risk of a subsequent explosion. The vapor/gas is heavier than air and will spread along
the ground. Vapors may accumulate in low or confined areas or travel a considerable
distance to a source of ignition and flash back.
Highly flammable liquid and vapor. Runoff to sewer may create fire or explosion hazard.
In a fire or if heated, a pressure increase will occur and the container may burst, with the
risk of a subsequent explosion. The vapor/gas is heavier than air and will spread along
the ground. Vapors may accumulate in low or confined areas or travel a considerable
distance to a source of ignition and flash back.
Fire Hazard
Keep away from heat and sources of ignition.
Flash back possible over considerable distance.
Beware of vapours accumulating to form explosive concentrations. Vapours can
accumulate in low areas.
|
| Hazardous combustion products |
Carbon oxides nitrogen oxides (NOx) Sulphur oxides Oxides of phosphorus |
| Special protective equipment for firefighters |
Use personal protective equipment.
spray to keep fire-exposed containers cool.Promptly isolate the scene by removing all persons from the vicinity of the incident if
there is a fire. No action shall be taken involving any personal risk or without suitable
training. Move containers from fire area if this can be done without risk. Use water
spray to keep fire-exposed containers cool.
|
| Specific extinguishing methods | Use water spray to cool unopened containers. Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations. In the event of fire and/or explosion do not breathe fumes. |
| Personal precautions, protective equipment and emergency procedures | Ensure adequate ventilation. Remove all sources of ignition. Keep people away from and upwind of spill/leak. Avoid inhalation, ingestion and contact with skin and eyes. When workers are facing concentrations above the exposure limit they must use appropriate certified respirators. Ensure clean-up is conducted by trained personnel only. Refer to protective measures listed in sections 7 and 8. |
| Environmental precautions | Do not allow contact with soil, surface or ground water. |
| Methods and materials for containment and cleaning up | Eliminate all ignition sources if safe to do so. Stop leak if safe to do so. Contain spillage, and then collect with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and place in container for disposal according to local / national regulations (see section 13). For large spills, dike spilled material or otherwise contain material to ensure runoff does not reach a waterway. Flush away traces with water. |
| Advice on safe handling | Take necessary action to avoid static electricity discharge (which might cause ignition of organic vapours). Do not ingest. Keep away from fire, sparks and heated surfaces. Do not breathe dust/fume/gas/mist/vapours/spray. Do not get in eyes, on skin, or on clothing. Wash hands thoroughly after handling. Use only with adequate ventilation. |
| Conditions for safe storage | Keep away from heat and sources of ignition. Keep in a cool, well-ventilated place. Keep away from oxidizing agents. Keep out of reach of children. Keep container tightly closed. Store in suitable labelled containers. Avoid direct sunlight. At temperatures greater than 30°C a component of this product may degrade leading to the production of hydrogen sulfide (H2S). |
| Suitable material | Keep in properly labelled containers |
| Unsuitable material | not determined |
Components with workplace control parameters
| Components | CAS-No | Form of exposure | Permissible concentration | Basis | ||
| Ethylene Glycol | 107-21-1 | TWA (Vapour.) |
|
ACGIH | ||
| STEL (Vapour.) | 50 ppm | ACGIH | ||||
|
STEL (Inhalable
fraction, Aerosol
only)
|
10 mg/m3 | ACGIH | ||||
| Methanol | 67-56-1 | TWA | 200 ppm | ACGIH | ||
| STEL | 250 ppm | ACGIH | ||||
| TWA |
200 ppm
260 mg/m3
|
NIOSH REL | ||||
| STEL |
250 ppm
325 mg/m3
|
NIOSH REL | ||||
| TWA |
200 ppm
260 mg/m3
|
OSHA Z1 | ||||
| 2-Mercaptoethanol | 60-24-2 | TWA | 0.2 ppm | AIHA WEEL | ||
| Isopropanol | 67-63-0 | TWA | 200 ppm | ACGIH | ||
| STEL | 400 ppm | ACGIH | ||||
| TWA |
400 ppm
980 mg/m3
|
NIOSH REL | ||||
| STEL |
500 ppm
1,225 mg/m3
1,225 mg/m3500 ppm
1,225 mg/m3
|
NIOSH REL | ||||
| TWA |
400 ppm
980 mg/m3
|
OSHA Z1 |
| Engineering measures | Effective exhaust ventilation system. Maintain air concentrations below occupational exposure standards. |
Personal protective equipment
| Eye protection |
Safety goggles Face-shield |
| Hand protection |
Wear the following personal protective equipment:
butyl-rubber
Gloves should be discarded and replaced if there is any indication of
degradation or chemical breakthrough.
|
| Skin protection | Personal protective equipment comprising: suitable protective gloves, safety goggles and protective clothing |
| Respiratory protection |
When workers are facing concentrations above the exposure limit they must use
appropriate certified respirators.
Combined inorganic gas/vapour and organic vapour type
|
| Hygiene measures |
Handle in accordance with good industrial hygiene and safety practice. Remove
and wash contaminated clothing before re-use. Wash face, hands and any
exposed skin thoroughly after handling. Provide suitable facilities for quick
drenching or flushing of the eyes and body in case of contact or splash hazard
|
The Personal Protective Equipment (PPE) recommendations provided above have been made in good faith based on typical expected conditions of use. PPE selection should always be completed in conjunction with a proper risk assessment and in accordance with a PPE management program.
| Appearance | liquid |
| Colour | opaque dark brown |
| Odour | : amine-like |
| Flash point | 41.0 °C, Method: ASTM D 93, PMCC |
| pH | 7.57, (20.0 °C), (undiluted) |
| Odour Threshold | no data available |
| Melting point/freezing point | Melting point/freezing point: -40.0 °C |
| Initial boiling point and boiling range | 82.50 °C |
| Evaporation rate | no data available |
| Flammability (solid, gas) | Not applicable. |
| Upper explosion limit |
no data available
materials.Extremely flammable in the presence of the following materials or conditions: oxidizing
materials.
|
| Lower explosion limit |
no data available |
| Vapour pressure | 50 hPa, (20.0 °C), |
| Relative vapour density | no data available |
| Relative density | 1.036, (20.0 °C), |
| Density | no data available |
| Water solubility | completely soluble |
| Solubility in other solvents | no data available |
| Partition coefficient: noctanol/water | no data available |
| Auto-ignition temperature | no data available |
| Thermal decomposition | no data available |
| Viscosity, dynamic | no data available |
| Viscosity, kinematic | 101.9 mm2/s (40.0 °C) |
| Molecular weight | no data available |
| VOC | no data available |
| Reactivity | No dangerous reaction known under conditions of normal use. |
| Chemical stability | At temperatures greater than 30°C a component of this product may degrade leading to the production of hydrogen sulfide (H2S). |
| Possibility of hazardous reactions | No dangerous reaction known under conditions of normal use |
| Conditions to avoid | Heat, flames and sparks. |
| Incompatible materials |
Strong oxidizing agents
|
| Hazardous decomposition products |
In case of fire, hazardous decomposition products may be produced such as:
Carbon oxides
nitrogen oxides (NOx)
Sulphur oxides
Oxides of phosphorus
Hydrogen sulfide (H2S)
|
| Information on likely routes of exposure | Inhalation, Eye contact, Skin contact |
Potential Health Effects
| Eyes |
Causes serious eye damage. |
| Skin | Harmful in contact with skin. Causes severe skin burns. May cause allergic skin reaction. |
| Ingestion | May cause blindness if swallowed. Harmful if swallowed. Causes digestive tract burns. |
| Inhalation | Harmful if inhaled. May cause nose, throat, and lung irritation. |
| Chronic Exposure | May cause cancer. May cause damage to organs. May cause damage to organs through prolonged or repeated exposure. |
Experience with human exposure
| Eye contact | Redness, Pain, Corrosion. |
| Skin contact | Redness, Pain, Irritation, Corrosion, Allergic reactions |
| Ingestion | Corrosion, Abdominal pain |
| Inhalation | Respiratory irritation, Cough |
Toxicity
Product
| Acute oral toxicity | Acute toxicity estimate: 542.32 mg/kg. |
| Acute inhalation toxicity | Acute toxicity estimate: 18.14 mg/l Exposure time: 4 h Test atmosphere: vapour |
| Acute dermal toxicity | Acute toxicity estimate: 1,411 mg/kg |
| Skin corrosion/irritation | No specific data. |
| Serious eye damage/eye irritation | no data available |
| Respiratory or skin sensitization | no data available |
| Carcinogenicity | no data available |
| Reproductive effects | no data available |
| Germ cell mutagenicity | no data available |
| Teratogenicity | no data available |
| STOT - single exposure | no data available |
| STOT - repeated exposure : | no data available |
| Aspiration toxicity | no data available |
Ecotoxicity
| Environmental Effects | Toxic to aquatic life with long lasting effects |
|
Components Toxicity to fish |
Alkylpyridine
LC50 Oncorhynchus mykiss (rainbow trout): 2.96 mg/l
Exposure time: 96 h
Ethylene Glycol
LC50: 72,860 mg/l
Exposure time: 96 h
Methanol
LC50: 15,400 mg/l
Exposure time: 96 h
Ethoxylated Mono-Tallow Alkyl-Amine
LC50 Fish: 1.1 mg/l
Exposure time: 96 h
2-Mercaptoethanol
LC50 Leuciscus idus (Golden orfe): 37 mg/l
Exposure time: 96 h
Isopropanol
LC50 Pimephales promelas (fathead minnow): 9,640 mg/l
Exposure time: 96 h
|
|
Components Toxicity to daphnia and other aquatic invertebrates |
Alkylpyridine
EC50 Daphnia magna (Water flea): 68.6 mg/l
Exposure time: 48 h
Ethylene Glycol
EC50 : > 100 mg/l
Exposure time: 48 h
Methanol
EC50 : > 10,000 mg/l
Exposure time: 48 h
Ethoxylated Mono-Tallow Alkyl-Amine
LC50 Aquatic Invertebrate: 2.6 mg/l
Exposure time: 48 h
2-Mercaptoethanol
EC50 Daphnia magna (Water flea): 0.4 mg/l
Exposure time: 48 h
Isopropanol
LC50 Daphnia magna (Water flea): > 10,000 mg/l
|
|
Components Toxicity to algae |
Alkylpyridine
EC50 Scenedesmus capricornutum (fresh water algae): 61.2
mg/l
Exposure time: 72 h
Ethylene Glycol
EC50 : 6,500 mg/l
Exposure time: 96 h
Methanol
EC50 : 22,000 mg/l
Exposure time: 72 h2-Mercaptoethanol
EC50 Desmodesmus subspicatus (green algae): 19 mg/l
Exposure time: 72 h
NOEC Desmodesmus subspicatus (green algae): 1.7 mg/l
Exposure time: 72 h
|
|
Components Toxicity to bacteria |
Ethylene Glycol
> 1,995 mg/l
Methanol
> 1,000 mg/l
Isopropanol
1,050 mg/l
|
|
Components Toxicity to fish (Chronic toxicity) |
Ethylene Glycol NOEC: 15,380 mg/l Exposure time: 7 d Methanol NOEC: 7,900 mg/l Exposure time: 8.3 d |
|
Components Toxicity to daphnia and other aquatic invertebrates (Chronic toxicity) |
Alkylpyridine
NOEC: 22.2 mg/l
Exposure time: 21 d
Species: Daphnia magna (Water flea)
Ethylene Glycol
NOEC: 8,590 mg/l
Exposure time: 7 d
2-Mercaptoethanol
NOEC: 0.063 mg/l
Exposure time: 21 d
Species: Daphnia magna (Water flea)
|
| Persistence and degradability | No data available |
| Mobility | no data available |
| Bioaccumulative potential | No data available |
| Other information | No data available . |
The information presented only applies to the material as supplied. The classification or waste code may not apply if the material has been used or otherwise contaminated. It is the responsibility of the waste generator to determine the toxicity and physical properties of the material generated at the time of disposal to determine the proper waste identification and disposal methods in compliance with applicable regulations.
| Disposal methods | The product should not be allowed to enter drains, water courses or the soil. Where possible recycling is preferred to disposal or incineration. If recycling is not practicable, dispose of in compliance with local regulations. Dispose of wastes in an approved waste disposal facility. |
| Disposal considerations | Dispose of as unused product. Empty containers should be taken to an approved waste handling site for recycling or disposal. Do not re-use empty containers. |
The shipper/consignor/sender is responsible to ensure that the packaging, labeling, and markings are in compliance with the selected mode of transport.
|
Land transport (DOT)
Proper shipping name
Technical name(s)
UN/ID No.
Transport hazard class(es)
Packing group
Proper shipping name
Technical name(s)
UN/ID No.
Transport hazard class(es)
Packing group
|
FLAMMABLE LIQUID, CORROSIVE, N.O.S
Ethylene Glycol, Oxydiethylenebis(Coco Alkyl-Dimethyl-Ammonium Chloride)
UN 2924
3, 8
III
FLAMMABLE LIQUID, CORROSIVE, N.O.S
Ethylene Glycol, Oxydiethylenebis(Coco Alkyl-Dimethyl-Ammonium Chloride)
UN 2924
3, 8
III
|
|
Air transport (IATA)
Proper shipping name
Technical name(s)
UN/ID No.
Transport hazard class(es)
Packing group
|
FLAMMABLE LIQUID, CORROSIVE, N.O.S.
Ethylene Glycol, Oxydiethylenebis(Coco Alkyl-Dimethyl-Ammonium Chloride)
UN 2924
3, 8
III
|
|
Sea transport (IMDG/IMO) Proper shipping name
Technical name(s)
UN/ID No.
Transport hazard class(es)
Packing group |
FLAMMABLE LIQUID, CORROSIVE, N.O.S.
Ethylene Glycol, Oxydiethylenebis(Coco Alkyl-Dimethyl-Ammonium Chloride)
UN 2924
3, 8
III
|
| *Marine pollutant | Oxydiethylenebis(Coco Alkyl-Dimethyl-Ammonium Chloride), Ethoxylated MonoTallow Alkyl-Amine |
EPCRA - Emergency Planning and Community Right-to-Know Act
CERCLA Reportable Quantity
EPCRA - Emergency Planning and Community Right-to-Know Act
CERCLA Reportable Quantity
| Components | CAS-No. | Component RQ (lbs) | Calculated product RQ (lbs) |
| Ethylene Glycol | 107-21-1 | 5000 | 50759 |
SARA 304 Extremely Hazardous Substances Reportable Quantity
This material does not contain any components with a section 304 EHS RQ.
| SARA 311/312 Hazards |
FLAMMABLE LIQUID, CORROSIVE, N.O.S.
Flammable (gases, aerosols, liquids, or solids)
Respiratory or skin sensitisation
Acute toxicity (any route of exposure)
Skin corrosion or irritation
Serious eye damage or eye irritation
Carcinogenicity
Specific target organ toxicity (single or repeated exposure)
|
|
SARA 302 |
No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302. |
| SARA 313 | The following components are subject to reporting levels established by SARA Title III, Section 313: Ethylene Glycol 107-21-1 9.8505 % Methanol 67-56-1 7.9102 % |
California Prop. 65
WARNING: Reproductive Harm - www.P65Warnings.ca.gov
Ethylene Glycol 107-21-1
Methanol 67-56-1
INTERNATIONAL CHEMICAL CONTROL LAWS :
United States TSCA Inventory
On the inventory, or in compliance with the inventory
| Other Information |
The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and weassume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Rx Marine International has been advised of the possibility of such damages. DISCLAIMER OF LIABILITY :The information in this SDS was obtained from sources which we believe are reliable. However, the information is provided without any warranty, express or implied, regarding its correctness. The conditions or methods of handling, storage, use or disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way connected with the handling, storage, use or disposal of the product. This MSDS was prepared and is to be used only for this product. If the product is used as a component in another product, this MSDS information may not be applicable. |