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SILICONE SEALENT


Wrench & Tools-65

SILICONE SEALENT

Part No: RXSOL-65-6502-001

DI OCTYL PHOSPHORIC ACID

Application
PRODUCT NAME    DIOCTYLPHOSPHORICACID
CAS number    298-07-7
UN number    1902
Formula     [C4H9CH(C2H5)CH2]2HPO4
Odour     
Solubility in water   INSOLUBLE
Density       0.973   at 25 oC
Boiling point    oC
Melting point    -60oC
Viscosity     
Flashpoint      196 oC
Explosive limits     
Vapour pressure    
Skin absorption/irritation    YES
TLV       Country        
Pollution category    1994   C
Dosage

MSDS

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Product Name               DI OCTYL PHOSPHORIC ACID
Part Number   RXSOL-19-1148-050

Company Details:

RX MARINE INTERNATIONAL
105, A wing , BSEL , TECH PARK.
VASHI ,NEW BOMBAY 400703 INDIA

Branch : Kandla, Mumbai , Chennai, Vizag, Kolkata, UAE , OMAN , CANADA and KENYA  

Phone +91 22 20871200 - 1400
Fax +91 22 27612100 :::AOH :0091 9821214367
Email mail @ rxmarine.com
Website www.rxmraine.comA

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Chemical  Name                            CAS                    EC number              Weight             Formula 
Dioctyl Phosphoric acid 3115-39-7 221-485-7 <= 100 %        C16H35O4P  

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Signal Word  Danger
Hazard Statements H301 H315 H318 H335 Toxic if swallowed. Causes skin irritation. Causes serious eye damage. May cause respiratory irritation.
Precautionary statements   P280 P261 P301/P310 P305/P351/P338 Wear protective gloves/protective clothing/eye protection/face protection. Avoid breathing dust/fume/gas/mist/vapours/spray IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do - continue rinsing.
Classification of the substance or mixture Not a hazardous substance or mixture according to Regulation (EC) No 1272/2008.
Supplemental Hazard      Statements None.
Other hazards  This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.

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General advice If medical attention is required, show this safety data sheet to the doctor.
If inhaled  If inhaled, move person to fresh air. If not breathing, give artificial respiration and consult a physician.
Eye Contact Immediately rinse eyes with plenty of water for at least 15 minutes. Consult a physician.
Swallowed Never give anything by mouth to an unconscious person. Rinse mouth with water. Do NOT induce vomiting unless advised to do so by a physician or Poison Control Center. Seek medical attention.
Skin Contact Wash affected area with soap and water. Consult a physician if any exposure symptoms are observed.
Inhalation Remove patient to fresh air, keep warm and at rest and get medical assistance in necessary. 
Ingestion Rinse mouth with water. Do not induce vomiting. Never give anything by mouth to an unconscious person. Call a doctor or Poison Control Center immediately.
Most important symptoms and effects, both acute and delaye No data available
Indication of any immediate medical attention and special treatment needed  No data available

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Flammability                                                  Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
Suitable extinguishing media Carbon dioxide (CO2) Foam Dry powder
Unsuitable extinguishing media For this substance/mixture no limitations of extinguishing agents are given.
Special hazards arising from the substance or mixture  Carbon oxides, Phosphorous oxides
Further information No data available.
Hazardous combustion
products
Fire may cause the evolution of Sulphur oxides, nitrogen oxides.
Advice for firefighters Wear self contained breathing apparatus for fire fighting if necessary. Use personal protection equipment.
Protective Equipment Use personal protective equipment.
Specific Hazards Arising from the Chemical Oxides of phosphorus Sodium oxides Not combustible. Fire may cause evolution of: Oxides of phosphorus Ambient fire may liberate hazardous vapours.

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Personal precautions, protective equipment and emergency procedures Wear respiratory protection. Avoid dust formation. Avoid breathing vapours, mist or gas. Ensure adequate ventilation. Evacuate personnel to safe areas. Avoid breathing dust. Avoid contact with skin, eyes or clothing.
Spillage Oxidizing material. Stop leak if without risk. Avoid contact with a combustible material (wood, paper, oil, clothing...). Keep substance damp using water spray. Do not touch spilled material. Prevent entry into sewers, basements or confined areas dike if needed. Eliminate all ignition sources. Call for assistance on disposal.
Enviromental Precaution Prevent further leakage or spillage if safe to do so. Do not let product enter drains.
Methods and materials for
containment and cleaning
Pick up and arrange disposal without creating dust. Sweep up and shovel. Keep in suitable, closed containers for disposal.

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Advice on protection against fire and explosion Keep away from open flames, hot surfaces and sources of ignition.Take precautionary measures against static discharge.
Incompatible materials  Keep away from alkalis, strong oxidizing agents and metals. Provide containment walls of adequate capacity to hold any accidental spills. 
Hygiene measures Immediately change contaminated clothing. Apply preventive skin protection. Wash hands and face after working with substance. For precautions see section 2.2.
Precautions for     safe handling Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Provide appropriate exhaust ventilation at places where dust is formed.
Storage conditions Keep container tightly closed in a dry and well-ventilated place. Keep in a dry place.
Storage class Storage class (TRGS 510): 3: Flammable liquids
Specific end     use(s) For scientific research and development only. Not for use in humans or animals.
Advice on general occupational hygiene Advice on safe handling Observe label precautions. Change contaminated clothing. Wash hands after working with substance.
Requirements for storage  Keep in cool and store under shade. 

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Exposure controls  Appropriate engineering controls Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday. 
Control parameters Contains no components with established occupational exposure limits.
Engineering Control A laboratory fumehood or other appropriate form of local exhaust ventilation should be used to avoid exposure.
Eye/face protection Safety goggles or face shield. All equipment should have been tested and approved under appropriate standards, such as NIOSH (US), CSA (Canada), or EN 166 (EU).
Body Protection Fire resistant (Nomex) lab coat or coveralls.
Skin protection Gloves should be used when handling this material. Gloves are to be inspected prior to use. Contaminated gloves are to be removed using proper glove removal technique so that the outer surface of the glove does not contact bare skin. Dispose of contaminated gloves after use in compliance with good laboratory practices and local requirements. Gloves used for incidental exposures (splash protection) should be designated as “chemical resistant” by EU standard EN 374 with the resistance codes corresponding to the anticipated use of the material. Unrated gloves are not recommended. Suggested gloves: AnsellPro Sol-Vex nitrile gloves style 37-175, 15 mil thickness. Penetration time has not been determined. Gloves used for prolonged direct exposure (immersion) should be designated “chemical resistant” as per EN 734 with the resistance codes corresponding to the anticipated use of the material. Suggested gloves: AnsellPro Viton/Butyl gloves style 38-612, 4/8 mil thickness. Penetration time has not been determined. These recommendations may not apply if the material is mixed with any other chemical, or dissolved into a solution. A risk assessment must be performed to ensure the gloves will still offer acceptable protection.
Respiratory protection Recommended respirators are NIOSH-approved N100 or CEN-approved FFP3 particulate respirators. These are to be only used as a backup to local exhaust ventilation or other engineering controls. If the respirator is the only means of protection, a full-face supplied air respirator must be used.
Other Protection      Measure Handle in accordance with good industrial hygiene and safety practice.
Control of    environmental exposure Do not let product enter drains. Risk of explosion.

                                                                                     gloves                suit                

                                                                                        Gloves                       Suit     

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Physical state Off-White Low-Melting Solid
Colour No data available
Odour No data available
Odor Threshold No data available
pH No data available
Melting Point No data available
Boiling Point No data available
Flash Point No data available
Evaporation Rate Not Applicable
Flammability (solid, gas) No data available
Explosive limits No Data Available
Upper/lower flammability or explosive limits No data available
Autoignition temperature No data available
Decomposition temperature  No data available
Vapour pressure No data available   
Density No data available                                                             
Relative  Density                                                     No data available
Relative vapor density No data available
Freezing point  No data available 
Viscosity dynamic No data available
Partition coefficient No data available
Explosive properties No data available 
Solubility No data available
Ignition temperature No information available.
Particle characteristics No data available 

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Reactivity                        No data available
Stability Stable under recommended storage conditions.   
Possibility of hazardous reactions Caution! In contact with nitrites, nitrates, nitrous acid possible liberation of nitrosamines! Exothermic reaction with: Nitriles Acid anhydrides acids nitrous acid
Conditions to avoid Warming.
Incompatible materials Strong oxidizing agents.
Hazardous decomposition products No data available

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Acute toxicity  No data available
Skin corrosion/irritation May be harmful if absorbed through skin. Causes skin irritation.
Serious eye      damage/eye       irritation  Causes severe eye burns and possible permanent eye damage.
Respiratory or skin    sensitization  In vivo assay - Mouse Result: Does not cause skin sensitization. Remarks: (ECHA)
Toxic Effects on         Human May cause damage to the following organs: upper respiratory tract. Other Toxic Effects on Humans: Hazardous in case of skin contact (irritant, sensitizer), of ingestion, of inhalation (lung irritant, lung sensitizer).
Carcinogenicity No data available
Germ cell        mutagenicity  No data available
Reproductive toxicity  No data available
Specific target organ toxicity - single      exposure No data available
Special Remarks on other Toxi  Effects on Humans Acute Potential Health Effects: Skin: Causes skin irritation. May cause skin sensitization, an allergic reation, which becomes evident upon re-exposure to this material. Eyes: Causes eye irritation. Ingestion: Causes gastrointestinal (digestive) tract irritation with nausea, vomiting, and diarrhea. May be harmful if swallowed. Inhalation: Causes respiratory tract irritation. May cause chemical pneumonitis and pulmonary edema, inflammation, edema of bronchi and larynx. Chronic Potential Health Effects: Repeated or prolonged skin exposure may cause allergic reactions in sensitive individuals. Repeated or prolonged exposure by inhalation may affect respiration and metabolism.
Endocrine disrupting properties The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher. Repeated dose toxicity - Rat - male and female - Oral - 14 d - NOAEL (No observed adverse effect level) - 300 mg/kg RTECS: JL9200000 Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin., Cough, Shortness of breath, Headache, Nausea To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

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Bioaccumulative potential No data available
Persistence and            degradability Biodegradability aerobic - Exposure time 28 d Result: 97 - 99 % - Readily biodegradable. (OECD Test Guideline 301B) Ratio BOD/ThBOD > 90 %
Toxicity to fish  Semi-static test LC50 - Oryzias latipes - 27 mg/l - 96 h (OECD Test Guideline 203)
Toxicity to daphnia and other aquatic invertebrates Static test EC50 - Daphnia magna (Water flea) - 73,34 mg/l - 48 h (Regulation (EC) No. 440/2008, Annex, C.2) 
Toxicity to algae Static test ErC50 - Desmodesmus subspicatus (green algae) - 11,8 mg/l - 72 h (DIN 38412)
Toxicity to bacteria  Static test EC50 - activated sludge - > 1.000 mg/l - 30 min (OECD Test Guideline 209)
Mobility in soil No Information available
Results of PBT and vPvB assessment This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.
Endocrine disrupting       properties The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher.
Other adverse effects No data available

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Disposal methods The material can be disposed of by removal to a licensed chemical destruction plant or by controlled incineration with flue gas scrubbing. Do not contaminate water, foodstuffs, feed or seed by storage or disposal. Do not discharge to sewer systems.
Contaminated packaging Dispose of as above.
Waste treatment      Method Product may be burned in an incinerator equipped with afterburner and scrubber. Excess and expired materials are to be offered to a licensed hazardous material disposal company. Ensure that all Federal and Local regulations regarding the disposal and destruction of this material are followed.

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UN number ADR/RID: 2810       IMDG:2810            IATA:2810  
UN proper shipping name ADR/RID:Phosphoric Acid Dioctyl         IMDG: Phosphoric Acid Dioctyl            IATA:Phosphoric Acid Dioctyl 
Transport hazard class(es) ADR/RID: 6.1           IMDG:6.1               IATA: 6.1
Packaging group ADR/RID:   III           IMDG:  III               IATA:  III
Environmental hazards ADR/RID:  NO         IMDG: NO            IATA: NO
Further information No data available                                                                                                                                  

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Inventory status Components are on the following inventories: Polymaleic acid: - US TSCA, Canadian DSL, EU EINECS, Australian AICS, Korean, Philippine PICCS and Chinese Xi irritant R 36/38 Irritant to eyes & skin R 41 Risk of serious damage to eyes S24/25 Avoid contact with skin and eyes S26/28 In case of contact eyes & skin, rinse with plenty water and seek medical advice Section 312/313: Not listed. Not listed under California proposition 65. 
Safety, health and environmental regulations/legislation specific for the substance or mixture This material safety data sheet complies with the requirements of Regulation (EC) No. 1907/2006.
National legislation Seveso III: Directive 2012/18/EU of the European Parliament and of the Council on the control of major-accident hazards involving dangerous substances. : ACUTE TOXIC : FLAMMABLE LIQUIDS
Other regulations Observe work restrictions regarding maternity protection in accordance to Dir 92/85/EEC or stricter national regulations where applicable. Take note of Dir 94/33/EC on the protection of young people at work.
Chemical Safety Assessment For this product a chemical safety assessment was not carried out

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Other Information

The information above is believed to be accurate and represents the  best information   currently    available  to us.  However,   we   make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and  weassume  no liability resulting from its use. Users should make  their  own  investigations  to determine the suitability of the information for their particular purposes. In no event shall be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Rx Marine International  has been advised of the possibility of such damages.

DISCLAIMER OF LIABILITY :The information in this SDS was obtained from sources which we believe are reliable. However, the information is provided without any warranty, express or implied, regarding its correctness. The conditions or methods of handling, storage, use or disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way connected with the handling, storage, use or disposal of the product. This MSDS was prepared and is to be used only for this product. If the product is used as a component in another product, this MSDS information may not be applicable.